(S)-(-)-1,1'-BI-2-NAPHTHOL |
PRODUCT
IDENTIFICATION
|
CAS
NO. |
18531-94-7 |
|
EINECS
NO. |
|
FORMULA |
C20H14O2 |
MOL
WT. |
286.33 |
H.S.
CODE
|
|
TOXICITY
|
|
SYNONYMS |
S-(-)-2,2'-Dihydroxy-1,1'-dinaphthyl; |
(S)-(-)-1,1'-Binaphthalene-2,2'-diol;
(S)-Binol; (-)-2,2'-Dihydroxy-1,1'-dinaphthyl; |
DERIVATION
|
|
CLASSIFICATION
|
|
PHYSICAL
AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
off-white
crystals
|
MELTING
POINT |
205 - 211 C |
BOILING
POINT |
|
SPECIFIC
GRAVITY |
|
SOLUBILITY
IN WATER |
|
pH |
|
VAPOR
DENSITY |
|
AUTOIGNITION
|
|
NFPA
RATINGS
|
Health: 2 Flammability: 0 Reactivity: 0 |
REFRACTIVE
INDEX
|
|
FLASH
POINT |
|
STABILITY |
Stable
under ordinary conditions. Hygroscopic. |
GENERAL
DESCRIPTION
|
An
effective chiral auxiliary used in the catalytic asymmetric oxidation of sulfides to
sulfoxides. Derivatives of binaphthol are used in asymmetric
rearrangements, epoxidations.reductions.
|
SALES
SPECIFICATION |
APPEARANCE
|
off-white
crystals
|
CHEMICAL
PURITY
|
99.5%
min |
OPTICAL
PUIRTY
|
99.5%
min e.e. |
TRANSPORTATION |
PACKING |
|
HAZARD
CLASS |
|
UN
NO. |
|
OTHER
INFORMATION |
Hazard Symbols: XI, Risk Phrases: 36/37/38,
Safety Phrases: 22-24/25 Optical
Rotation: -35°
~ -36° (C=1, THF) |
|