R-(-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE

PRODUCT IDENTIFICATION

CAS NO. 39648-67-4

R-(-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE

EINECS NO.

 

FORMULA C20H13O4P
MOL WT. 348.29

H.S. CODE

 

TOXICITY

 

DERIVATION

 

SYNONYMS R-(-)-1,1[-Binaphthyl-2,2]-diyl hydrogenphosphate;
(R)-(-)-1,1'-Binaphthalene-2,2'-diyl hydrogen phosphate; R-(-)-BNP Acid; (R)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-oxide;

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE

off-white powder

MELTING POINT

>300 C

BOILING POINT  
SPECIFIC GRAVITY  
SOLUBILITY IN WATER  
pH  
VAPOR DENSITY

 

AUTOIGNITION

 

NFPA RATINGS

Health: 1 Flammability: 0 Reactivity: 0

REFRACTIVE INDEX

 
FLASH POINT

 

STABILITY

Stable under ordinary conditions.

GENERAL DESCRIPTION

An effective chiral resolving agents for racemic amines. Its complexes with palladium and are rhodium are useful catalysts in asymmetric hydrocarboxylations and cycloadditions.
SALES SPECIFICATION

APPEARANCE

off-white powder

CHEMICAL PURITY

98.0% min

OPTICAL PUIRTY

98.0% min e.e.
TRANSPORTATION
PACKING
 
HAZARD CLASS  
UN NO.  
OTHER INFORMATION
Hazard Symbols: XI, Risk Phrases: 36/37/38, Safety Phrases: 26-36
Optical Rotation: -605
° (C=1, MeOH)