CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM

Synonyms. Chlorotris(triphenylphosphine)rhodium; Chlorotris(triphenylphosphine)rhodium(I); Tris(triphenylphosphine)chlororhodium; Tris(triphenylphosphine)chlororhodium(I); Tris(triphenylphosphine)rhodium chloride; Tris(triphenylphosphine)rhodium monochloride; Tris(triphenylphosphino)chlororhodium; Rhodium(I) tris(triphenylphosphine) chloride; Wilkinson's catalyst; Rhodium triphenylphosphane;chloride;

CHLOROTRIS(TRIPHENYLPHOSPHINE)RHODIUM

 

PRODUCT IDENTIFICATION

CAS RN

14694-95-2

EINECS RN

238-744-5

FORMULA

 [(C6H5)3P]3RhCl

MOLE WEIGHT

925.22

H.S CODE

 2843.90.0000

SMILES

 c1(ccccc1)P(c1ccccc1)c1ccccc1.c1(P(c2ccccc2)c2ccccc2)ccccc1 .c1(P (c2ccccc2)c2ccccc2)ccccc1.[Rh+].[ClH-]

CLASSIFICATION

Rhodium compound, Catalyst, Phosphine complex

EXTRA NOTES

Other RN: 27813-17-8, 35933-45-0, 63478-44-4

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE

red to violet crystals or powder

MELTING POINT

245 ~ 250 C

BOILING POINT

 

DENSITY

 

SOLUBILITY IN WATER

Insoluble

SOLVENT SOLUBILITY

Soluble in chloroform, acetone and alcohol

VAPOR DENSITY

 

log P(octanol-water)

  

VAPOR PRESSURE

  

AUTOIGNITION TEMP

  
pK

 

REFRACTIVE INDEX

 

FLASH POINT

 

 

STABILITY AND REACTIVITY
STABILITY Stable under normal conditions.

INCOMPATIBLE MATERIALS

Strong oxidizing agents.

POLYMERIZATION

Has not been reported

NFPA RATINGS

Health: 0, Flammability: 1, Reactivity: 0

 

EXTERNAL LINKS & GENERAL DESCRIPTION

USA.gov - Chlorotris(triphenylphosphine)rhodium

Wikipedia Linking - Wilkinson's catalyst

Google Scholar Search - Chlorotris(triphenylphosphine)rhodium

U.S. National Library of Medicine - Chlorotris(triphenylphosphine)rhodium

PubChem Compound Summary - Chlorotris(triphenylphosphine)rhodium

NCBI (http://www.ncbi.nlm.nih.gov/) -  Chlorotris(triphenylphosphine)rhodium

Material Safety Data Sheet - Chlorotris(triphenylphosphine)rhodium

EPA - Substance Registry Services - Chlorotris(triphenylphosphine)rhodium

http://www.sigmaaldrich.com/
Catalyst used for many organic reactions including:
·Chemoselective allylic alkylations
·Stoichiometric activation of Si-H bonds and hydrosilylations
·Inter- and intramolecular hydroacylation of alkenes along with a cocatalyst
·Polymerization of diorganostannanes

 

SALES SPECIFICATION

APPEARANCE

red to violet crystals or powder

PURITY

99.95% min

Ru CONTENT

11.0% min

 

TRANSPORT & REGULATORY INFORMATION

UN NO.

 

HAZARD CLASS

 

PACKING GROUP  

 

SAFETY INFORMATION

HAZARD OVERVIEW

GHS (Globally Harmonised System) Classification: Not a dangerous substance. Potential Health Effects: Eyes - May cause eye irritation. Skin - May be harmful if absorbed through skin May cause skin irritation. Inhalation - May be harmful if inhaled. May cause respiratory tract irritation. Ingestion - May be harmful if swallowed.

HAZARD CODES

 

RISK PHRASES

 

SAFETY PHRASES

 

 

PACKING

Preserved in light-resistant and well-closed bottles