DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM

Synonyms. Dichlorotris(triphenylphosphine)ruthenium; Chlorotri ruthenium; Ruthenium tris(triphenylphosphine) dichloride; Tris(triphenylphosphine)dichlororuthenium; Tris(triphenylphosphine)ruthenium dichloride; Tris(triphenylphosphine)ruthenium(II) dichloride; Ruthenium(2+) triphenylphosphane;dichloride;

DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM

 

PRODUCT IDENTIFICATION

CAS RN

15529-49-4

EINECS RN

239-569-7

FORMULA

C54H45Cl2P3Ru

MOLE WEIGHT

958.83

H.S CODE

2843.90.0000

SMILES

P(c1ccccc1)(c1ccccc1)c1ccccc1.P(c1ccccc1)(c1ccccc1) c1ccccc1. P(c1 cc ccc1) (c1ccccc1)c1ccccc1.[Ru+2].[ClH-].[ClH-]

CLASSIFICATION

Catalyst, Ruthenium compound

EXTRA NOTES

 

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE

red-brown to black crystalline powder

MELTING POINT

133 C

BOILING POINT

360 C

DENSITY

1.53 g/cm3

SOLUBILITY IN WATER

Insoluble

SOLVENT SOLUBILITY

Sparingly soluble in methanol, ethanol

VAPOR DENSITY

 

log P(octanol-water)

 

VAPOR PRESSURE

 

AUTOIGNITION TEMP

 
pK

 

REFRACTIVE INDEX

 

FLASH POINT

181 C

 

STABILITY AND REACTIVITY
STABILITY Stable under normal conditions.

INCOMPATIBLE MATERIALS

Strong oxidizing agents, moisture

POLYMERIZATION

Has not been reported

NFPA RATINGS

Health: 2, Flammability: 1, Reactivity: 0

 

EXTERNAL LINKS & GENERAL DESCRIPTION

USA.gov - Dichlorotris(triphenylphosphine)ruthenium

Wikipedia Linking - Dichlorotris(triphenylphosphine)ruthenium(II)

Google Scholar Search - Dichlorotris(triphenylphosphine)ruthenium

PubChem Compound Summary - Dichlorotris(triphenylphosphine)ruthenium

NCBI (http://www.ncbi.nlm.nih.gov/) -  Dichlorotris(triphenylphosphine)ruthenium

Material Safety Data Sheet - Dichlorotris(triphenylphosphine)ruthenium

http://www.sigmaaldrich.com/
Application:
· Catalyst employed in a synthesis of furans from allenyl sulfides.
· C-H Activation Catalyst in a Ruthenium/Lewis Acid System

 

SALES SPECIFICATION

APPEARANCE

red-brown to black crystalline powder

ASSAY

98% min

Ru CONTENT

10.5% min

 

TRANSPORT & REGULATORY INFORMATION

UN NO.

 

HAZARD CLASS

 

PACKING GROUP  

 

SAFETY INFORMATION

HAZARD OVERVIEW

GHS (Globally Harmonised System) Classification: Acute toxicity (Inhalation, Dermal, Oral). Hazard statements: Harmful if swallowed or in contact with skin. Harmful if inhaled.

SIGNAL WORD Warning

PICTOGRAMS

PICTOGRAM_GHS07_exclamation.jpg

HAZARD STATEMENTS

H302 + H312-H332

P STATEMENTS

P280-P302 + P352-P304 + P340

EC DIRECTIVES

 

HAZARD CODES

CODE_Xn_Xi_harmful_Irritant.gif

RISK PHRASES

20/21/22

SAFETY PHRASES

36/37

 

PACKING

Preserved in light-resistant and well-closed bottles

 

PRICE INFORMATION