TIRON

Synonyms. Tiron; 1,2-Dihydroxybenzene-3,5-disulfonic acid disodium salt; 3,5-Disulfocatechol disodium salt; 4,5-Dihydroxy-m-benzenedisulfonic acid disodium salt; Dihydroxy benzene disulfonate disodium salt; Disodium 1,2-dihydroxybenzene-3,5-disulfonate; Disodium 4,5-dihydroxy-1,3-benzenedisulfonate; Disodium 4,5-dihydroxy-m-benzenedisulfonate; Disodium 4,5-dihydroxybenzene-1,3-disulfonate; Disodium pyrocatechol-3,5-disulfonate; Sodium 1,2-dihydroxy-3,5-benzenedisulfonate; Sodium 1,2-dihydroxybenzenedisulfonate; Sodium 4,5-dihydroxybenzene-1,3-disulfonate; Sodium catechol sulfate; Sodium pyrocatechol-3,5-disulfonate; Tiferron;

1,2-Dihydroxybenzene-3,5-disulfonic acid

Click for original image

 

PRODUCT IDENTIFICATION

CAS RN

149-45-1 (anhydrous), 270573-71-2 (hydrate)

EINECS RN

205-741-5

FORMULA

(OH)2C6H2(SO3Na)2

MOLE WEIGHT

314.19

H.S CODE

2908.99.1200

SMILES

c1(cc(cc(c1O)O)S(=O)(=O)[O-])S(=O)(=O)[O-].[Na+].[Na+]

CLASSIFICATION

Indicator

EXTRA NOTES

A colorimetric reagent for iron, manganese, titanium, molybdenum, and complexes of zirconium. (From Merck Index, 11th ed) [MeSH]
Other RN: 479665-10-6, 149-46-2 (parent)

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE.

white to off-white crystalline powder

MELTING POINT

> 300 C

BOILING POINT

 

DENSITY

 

SOLUBILITY IN WATER

 

SOLVENT SOLUBILITY

 

VAPOR DENSITY

 

log P(octanol-water)

-3.07

VAPOR PRESSURE

 

AUTOIGNITION TEMP

 
pK

 

REFRACTIVE INDEX

 

FLASH POINT

 

 

STABILITY AND REACTIVITY
STABILITY Stable under normal conditions.

INCOMPATIBLE MATERIALS

Strong oxidizing agents

POLYMERIZATION

Has not been reported

NFPA RATINGS

Health: 2, Flammability: 0, Reactivity: 0

 

EXTERNAL LINKS & GENERAL DESCRIPTION

USA.gov - Tiron

Google Scholar Search - 1,2-Dihydroxybenzene-3,5-disulfonic acid disodium salt

U.S. National Library of Medicine - Tiron

PubChem Compound Summary - Tiron

KEGG (Kyoto Encyclopedia of Genes and Genomes) -  Tiron

http://www.ebi.ac.uk/ ChEMBL-  Tiron

http://www.ncbi.nlm.nih.gov/ -  Tiron

Material Safety Data Sheet - Tiron

EPA - Substance Registry Services - Tiron

 

SALES SPECIFICATION

APPEARANCE

white crystalline powder

ASSAY

98% min

WATER

6.0% max

ASH

0.2% max

LOSS ON DRYING

5% max

SULFATE

1.0% max

CHLORIDE

0.5% max

 

TRANSPORT & REGULATORY INFORMATION

UN NO.

 

HAZARD CLASS

 

PACKING GROUP  

 

SAFETY INFORMATION

HAZARD OVERVIEW

GHS (Globally Harmonised System) Classification: Skin irritation. Eye irritation. Specific target organ toxicity - single exposure. Hazard statements: Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

SIGNAL WORD Warning

PICTOGRAMS

PICTOGRAM_GHS07_exclamation.jpg

HAZARD STATEMENTS

H315-H319-H335

P STATEMENTS

P261-P305 + P351 + P338

EC DIRECTIVES

 

HAZARD CODES

CODE_Xn_Xi_harmful_Irritant.gif

RISK PHRASES

36/37/38

SAFETY PHRASES

26-36

 

PACKING

Preserved in light-resistant and well-closed bottles