Cyclohexane is the six-membered alicyclic
hydrocarbon consisting of six carbon atoms linked to each other to form a ring,
with each carbon atom bearing two hydrogen atoms, C6H12. A cyclic compound is an
organic compound that contains one or more closed rings of carbon atoms. The
term alicyclic refers to cyclic compound that behaves chemically like aliphatic
compounds (open-chain), which means the exclusion of carbocyclic compounds of
aromatic rings with an array of π-electrons characteristic. Cyclohexane is a
colorless, highly flammable, mobile liquid with a pungent odor. It is insoluble
in water and soluble in alcohol, ether, and almost organic solvents. Cyclohexane
is a non-corrosive and quick volatilize liquid and sublimes between -5 to 5 C.
Cyclohexane can exist in a number of interconvertible three-dimensional
conformations, the two simplest being are the chair and boat conformation and
others include the half-chair and twist-chair conformation. Cyclohexane can
cause irritation to the eyes and mucous membranes in workers. Repeated and
prolonged contact with skin may cause dermatitis. The substance has not been
shown to cause the hematologic changes associated with exposure to benzene.
Cyclohexane occurs naturally in crude oils. Some cyclohexane is recovered from
petroleum streams by fractionation. The bulky commercial production of
cyclohexane is based on hydrogenation of benzene in closed system. Cyclohexane
consumption is linked almost entirely to nylon production. Nylon is further
processed into fibers for applications in carpeting, automobile tire cord,
clothing, and other growing industrial fields. Cyclohexane is used as a solvent,
oil extractant, paint and varnish remover, dry cleaning material, and in solid
fuels. It has been used as a insecticide itself. Cyclohexane is used as a
chemical intermediate to produce target molecules. Natural compounds of one to
five alicyclic rings with great variety and complexity are found particularly in
steroids and terpenes. Cyclohexane structure, six membered-ring, is one of the
major skeleton in nature. Cyclohexane derivatives can be used for the synthesis
of pharmaceuticals, dyes, herbicides, plant growth regulator, plasticizers,
rubber chemicals, cycloamines and other organic compounds. Aldehyde is
an
organic compound containing -CHO radical, in which a carbon atom forms a double
bond with an oxygen atom and is also bonded to a hydrogen atom and another group
denoted by R, which can be a second hydrogen atom, an alkyl group, or an aryl
group. The most important and the simplest examples are methanal (formaldehyde),
HCOH, and ethanal (acetaldehyde), CH3CHO.( In systematic chemical
nomenclature, aldehyde names end with the suffix -al). Formaldehyde is used to
make synthetic resins by reaction with phenols, urea, and melamine, as a
chemical intermediate, as an embalming fluid, and as a disinfectant.
Acetaldehyde is used chiefly to manufacture acetic acid. They are
unpleasant-smelling liquids widely used in the chemical industry, whereas
aromatic aldehydes frequently have pleasant smells and are used widely as
flavourings and perfumes. An example is benzaldehyde (benzenecarbaldehyde,
C6H5CHO), a derivative of benzene with an aldehyde group
attached to the ring. It is a colourless oil smelling of almonds offer
applications to both in perfumes and flavourings. Aldehydes are formed by
oxidation of primary alcohols; further oxidation yields carboxylic acids.
Aldehydes can undergo certain characteristic addition and condensation reactions.
Aldehydes can be reduced to primary alcohols (ketones to secondary alcohols).
Aldehydes form cyanohydrins with hydrogen cyanide, acetals with alcohol,
yellow-orange solid derivatives with DNP ( 2,4-dinitrophenylhydrazones) and
undergo condensation reactions to yield oximes (compounds containing the group
C:NOH), hydrazones (organic compounds containing the group =C:NNH2),
and semicarbazones (organic compounds containing the unsaturated group
=C:N.NH.CO.NH2). Aldehydes readily polymerize. Compounds which do not have alpha-hydrogen atoms cannot form an enolate ion and
do not undergo electrophilic alpha-substitution and aldol condensation. Aromatic
aldehydes such as benzaldehyde and formaldehyde may undergo disproportionation
in concentrated alkali (Cannizaro's reaction); one molecule of the aldehyde is
reduced to the corresponding alcohol and another molecule is simultaneously
oxidized to the salt of a carboxylic acid. The speed of the reaction depends on
the substituents in the aromatic ring. Two different types of aldehydes
(aromatic and aliphatic) can undergo crossing reaction to form fomaldehyde and aromatic alcohols. |