COPPER (II) TETRAFLUOROBORATE

PRODUCT IDENTIFICATION

CAS NO. 38465-60-0

COPPER (II) TETRAFLUOROBORATE

EINECS NO. 253-959-4
FORMULA Cu(BF4)2
MOL WT. 237.16
H.S. CODE 2826.90.9000

TOXICITY

 
SYNONYMS Copper fluoborate; Copper(II) fluoborate;
copper(2+) tetrafluoro-borate(1-) (2:1); Kupfer(2+)tetrafluoroborat(1-) (German); Tetrafluoroborato(1-) de cobre(2+)  (Spanish); Tétrafluoroborate(1-) de cuivre(2+) (French); Cupric Fluoborate; Other RN: 13773-00-7, 14735-84-3, 188920-96-9, 188920-97-0

SMILES

[Cu+2].[B-](F)(F)(F)F.[B-](F)(F)(F)F

CLASSIFICATION

 

EXTRA NOTES

Starting material for homometallic, trinuclear heteroscorpionate complexes applied in studies of electronic and magnetic properties

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE

blue crystals

MELTING POINT

 

BOILING POINT  
SPECIFIC GRAVITY

 

SOLUBILITY IN WATER Readily soluble (Slightly soluble in alcohol)
pH  
VAPOR DENSITY 8.19
AUTOIGNITION

 

NFPA RATINGS

Health hazard: 3, Fire: 0, Reactivity Hazard: 0

REFRACTIVE INDEX

 
FLASH POINT Not considered to be a fire hazard
STABILITY Stable under ordinary conditions. Moisture sensitive.

EXTERNAL LINKS & GENERAL DESCRIPTION

Wikipedia Linking

Google Scholar Search

http://onlinelibrary.wiley.com/
Fluoroboric acid and the fluoroborates are commercially important to a variety of industries. The acid is used in plating circuits, in metal finishing, in the production of aluminum, and as an acid catalyst. Main group metal and ammonium fluoroborates find use as fluxes, as catalysts, and in flame-retardant manufacture. Transition- and other heavy-metal fluoroborate salts are used in the plating industry and as catalysts. Properties and manufacture are described.

http://ixian.ca/
Acid Fluoborate Copper Processes Copper fluoborate is much more soluble than copper sulfate. Therefore for high-current-density and high-speed processes, the copper-ion concentration can be more than double that obtainable in the sulfate baths. The fluoborate ion also helps provide solubility and conductivity. But when compared with sulfate baths, the fluoborate bath has less throwing power. The copper sulfate bath is more widely used than the fluoborate because it is less expensive. Also, many more additive systems have been developed for copper-sulfate formulations. Copper fluoborate baths are more hazardous to use and harder to waste treat than sulfate baths. And as with the sulfate baths, the fluoborate solutions are very corrosive, making careful design of plating equipment important. Chemistry of copper fluoborate baths. Table VII shows the composition of a typical acid copper fluoborate bath. If the fluoboric acid concentration is too low (pH above 1.7), the deposit may be dull, dark, and brittle. Add boric acid to stabilize the bath and to prevent the decomposition of the fluoborate to fluoride. The anode film and its care in a fluoborate bath are very similar to the requirements described for the copper sulfate bath

Local: Fluoroboric acid is used in plating circuits; metal finishing; electropolishing of aluminium and its alloy; component of galvanic baths; organic synthesis as catalyst for alkylations and polymerisation; stabilisation of diazo salts; manufacturing of inorganic fluoroborate salts.

Inorganic fluoroborate salts are used as components of fluxing and plating, as catalysts, in flame-retardant manufacture, in metal treatment; grain refining agents; as active fillers in resin bonded abrasives; in electrolytic generation of boron, preparation of glazing frits.

SALES SPECIFICATION (45% SOLUTION)

APPEARANCE

clear liquid

Cu(BF4)2

44 - 46.0%

FREE ACID

1.0% max

SO4

1.2% max

SiO2

0.5% max

Cl

0.1% max

HEAVY METAL

10ppm max

TRANSPORTATION
PACKING

50kg in drum

HAZARD CLASS 8 (Packing group:II)
UN NO. 3260
SAFETY INFORMATION

GHS

 

SIGNAL WORD

Danger

PICTOGRAMS

HAZARD STATEMENTS

H302 + H312 Harmful if swallowed or in contact with skin.
H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled.

PRECAUTIONARY STATEMENTS

P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.

EC DIRECTIVES

 

HAZARD CODES

C Corrosive

RISK PHRASES

20/21/22 Harmful by inhalation, in contact with skin and if swallowed
34  
Causes burns

SAFETY PHRASES

26  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39  
Wear suitable protective clothing, gloves and eye/face protection
45  
In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)

PRICE INFORMATION