DIISOPROPANOLAMINE

PRODUCT IDENTIFICATION
CAS NO. 110-97-4

DIISOPROPANOLAMINE

EINECS NO. 203-820-9
FORMULA [CH3CH(OH)CH2]2NH
MOL WT. 133.19
H.S. CODE 2922.19

TOXICITY

 Orl rat LD50: 4765 mg/kg
SYNONYMS Bis(2-hydroxypropyl)amine; DI(2-Hydroxy-n-propyl) amine;
1,1'-imino-bis(2-propanol); DIPA; 2,2'-dihydroxy-dipropyl-amine; 1,1'-iminodipropan-2-ol; Bis(2-hydroxypropyl)amine; Bis(2-propanol)amine; Dipropyl-2,2'-dihydroxy-amine;

SMILES

 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE Clear to yellow solid
MELTING POINT 44.5 - 45.5 C
BOILING POINT

248 - 249 C

SPECIFIC GRAVITY 1.004
SOLUBILITY IN WATER soluble

SOLVENT SOLUBILITY

 Soluble in methanol, acetone, ether
pH medium strong base
VAPOR DENSITY 4.6
AUTOIGNITION

370 C

NFPA RATINGS Health: 2 Flammability: 1 Reactivity: 0

REFRACTIVE INDEX

  
FLASH POINT 126 C
STABILITY Stable under ordinary conditions

DESCRIPTION AND APPLICATIONS
There are three isopropanolamines called mono, di and tri-propanolamine with formula with formula CH3CH(OH)CH2NH2, CH3CH(OH)CH2]2NH, and CH3CH(OH)CH2]3N respectively. Monoisopropanolamine is a liquid at room temperature, while diisopropanolamine and triisopropanolamine are white solids. Isopropanolamine is a clear to yellow, corrossive, combustible liquid with a faint ammonia odor; boils at 159.9 C. It is soluble in water and very soluble in benzene and ether. Diisopropanolamine is a clear to yellow hygroscopic crystalline lumps; boils at 241 C, decomposes on heating producing toxic nitrogen oxides. It is a medium strong base and reacts violently with strong oxidants. It turns yellow when exposed to light and air. Diisopropanolamine and triisopropanolamine are commercially available in liquid grades contain deionized water typically 15%. These liquid grades should not be stored in the presence of aluminum due to the possibility of excessive corrosion and potential chemical reaction releasing flammable hydrogen gas at above 60 C. Isopropanolamines are used as an absorbent of acid gases in the refinery of natural gas and purification of ammonia. They are used as an emulsifying agent soluble in water and low alkalinity. They are used as a crosslinking catalyst in the production of polyurethanes. They are used as a component of insecticide, surfactants, rubber chemicals, corrosion inhibitors and pigment dispersants.

Isopropanolamines have applications in the field of:  

  • Gas-scrubber
    • Natural and refinery gas operations
    • Hydrogen sulfide (H2S) and CO2 gas removal
  • Textile Operation
    • Softeners
    • Lubricants
    • Dye Leveling Agents
    • Dispersants
    • Durable Press
    • Optical Brighteners
  • Surfactants and  Metalworking fluids
    • Impart alkalinity
    • Detergents
    • Cosmetic formulations
    • Acid neutralization
    • Fatty acid soaps
    • Emulsifiers
    • Corrosion Inhibitors
  • Others
    • Concrete grinding aid
    • Cement admixture
    • Urethane foams
    • Agricultural products
    • Photographic chemicals
    • Biocides
    • Oil well chemicals
    • Rubber vulcanization accelerators
    • Plasticizers
    • Pigment Dispersant
    • Cross-Linker for Coatings
    • Asphalt aggregatation

 

MIPA

DIPA

TIPA

Formula

CH3CH(OH)CH2NH2

[CH3CH(OH)CH2]2NH

[CH3CH(OH)CH2]3N

MW

(75.11)

133.19

191.27

CAS RN

78-96-6

110-97-4

122-20-3

Appearance

Clear liquid

clear to light yellow crystals

Specific Gravity

0.96

1.015

1.02

Freezing Point C

3 - 4 C

44 - 45 C

48 - 52

Boiling point C

159

248 - 249

305 C

Flash Point C

73

135

160
SALES SPECIFICATION

SOLID

APPEARANCE

clear to yellow solid

CONTENT

98.0% min

MIPA, TIPA IMPURITY

1.5% max

WATER

0.5% max

85% AQ. SOLUTION

APPEARANCE

clear to yellow liquid

CONTENT

85.0% min

MIPA, TIPA IMPURITY

1.5% max

WATER

Balance

TRANSPORTATION
PACKING 190kgs in drum
HAZARD CLASS  
UN NO.  
OTHER INFORMATION