N-NITROSODIMETHYLAMINE |
PRODUCT
IDENTIFICATION
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CAS
NO. |
62-75-9 |
|
EINECS
NO. |
|
FORMULA |
C2H6N2O |
MOL
WT. |
74.08 |
H.S.
CODE |
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TOXICITY
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SYNONYMS |
N,N-dimethylnitrosamine; |
Dimethylnitrosamine; Dimethylnitrosoamine; DMN; DMNA;
Methamine, N-methyl-N-nitroso-; NDMA; Nitrosodimethylamine; Nitrous Ddimethylamide; N-methyl-N-nitroso-methanamine;
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SMILES
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CLASSIFICATION
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PHYSICAL AND CHEMICAL PROPERTIES
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PHYSICAL
STATE |
yellow oily liquid |
MELTING POINT |
50
C
|
BOILING
POINT |
151 - 154 C |
SPECIFIC GRAVITY |
1.01 |
SOLUBILITY
IN WATER |
soluble |
pH |
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VAPOR DENSITY |
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AUTOIGNITION
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NFPA
RATINGS
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REFRACTIVE
INDEX
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FLASH
POINT |
61
C
|
STABILITY |
Stable
under ordinary conditions
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APPLICATIONS
|
Nitroso
is the prefix for NO-
radical with trivalent nitrogen also known as hydroximino;
oximido. Substances in which this group is attached
to an oxygen atom are called nitrites (esters of nitrous
acid); those in which the nitroso group is attached
to a metal ion are called nitrosyls. Nitroso (-N=O)
groups and azo (-N=N-) groups impart colour to the compound
as these groups absorb light of characteristic wavelengths.
Nitroso groups are strongly electron withdrawing and more similar to the C=O
than the nirto group. Nitroso compound tends to dimerise. There is polarisation
of the N=O bond and so behaves as a weak C=O. It undergoes addition of
nucleophiles and condensation with primary amines and the anions of active
methylene compounds. Nitroso groups are useful in addition and condensation
reactions, stable nitroxide radical preparations, and isomerization to oxime.
Oxidation undergoes readily with peracids, this is not available with nitro
groups. Nitroso compounds are useful intermediates for the synthesis of target
materials. Certain niroso derivatives are used as vulcanization accelerator by direct
reacting with peroxy-free radical to tie up free radicals and adhesion
promoter between metal and rubber. N-Nitrosodialkylamines which have N-nitroso functional group (–N–N=O) and amine functions (–NR2)
are used as fire retardants in
rubber & plastic formulations and as intermediaits for synthesis of catalyst, antioxidant, additive for lubricants, and softener of
copolymers. N-Nitrosodimethylamine is also used in rocket fuels and
as a solvent. |
SALES
SPECIFICATION |
APPEARANCE
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yellow oily liquid |
ASSAY |
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MOISTURE |
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TRANSPORTATION |
PACKING |
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HAZARD CLASS |
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UN
NO. |
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OTHER
INFORMATION |
Hazard
Symbols: XN, Risk Phrases: 26/27/28-36/37/38, Safety Phrases: 45 |
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