2,4-XYLYLALDEHYDE |
PRODUCT
IDENTIFICATION
|
CAS
NO. |
15764-16-6 |
|
EINECS
NO. |
239-856-7 |
FORMULA |
(CH3)2C6H3CHO |
MOL
WT. |
134.18 |
H.S.
CODE
|
29219.90 |
TOXICITY |
|
SYNONYMS |
1-Formyl-2,4-dimethyl benzene; 2,4-Dimethylbenzaldehyde;
|
2,4-Dimethylbenzenecarboxaldehyde;
2,4-Dimetilbenzaldehído; 2,4-Diméthylbenzaldéhyde;
|
SMILES |
|
CLASSIFICATION
|
|
PHYSICAL
AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
Clear
liquid |
MELTING
POINT |
-9
C |
BOILING
POINT |
212
- 210 C at 710 mmHg |
SPECIFIC
GRAVITY |
0.962 |
SOLUBILITY
IN WATER |
|
pH |
|
VAPOR
DENSITY |
|
AUTOIGNITION
|
|
NFPA
RATINGS
|
|
REFRACTIVE
INDEX
|
1.5485 -
1.5505 |
FLASH
POINT |
88
C |
STABILITY |
stable
under ordinary conditions |
GENERAL
DESCRIPTION AND APPLICATIONS
|
Benzaldehyde(also
called Benzenecarbonal) is the simplest representative of the aromatic aldehydes.
It is a colorless liquid aldehyde with a characteristic almond odor. It
boils at 180°C, is soluble in ethanol, but is insoluble in water. Benzaldehyde
is formed
by partial oxidation of benzyl alcohol and readily oxidized to benzoic acid and is converted to
addition products by hydrocyanic acid or sodium bisulfite. It is also prepared by
oxidation of toluene or benzyl chloride or by treating benzal chloride with an
alkali, e.g., sodium hydroxide.
It is used chiefly in the synthesis of other organic compounds, ranging from pharmaceuticals to plastic
additives
and benzaldehyde is an important intermediate for the processing of perfume and flavouring
compounds and in the preparation of
certain aniline dyes . It is the first step in the synthesis for fragrances.
It undergoes
simultaneous oxidation and reduction with alcoholic potassium hydroxide, giving
potassium benzoate and benzyl alcohol. It is
converted to benzoin with alcoholic potassium cyanide, with anhydrous sodium acetate and acetic anhydride, giving cinnamic acid.
Compounds which do not have alpha-hydrogen atoms cannot form an enolate ion and
do not undergo electrophilic alpha-substitution and aldol condensation. Aromatic
aldehydes such as benzaldehyde and formaldehyde may undergo disproportionation
in concentrated alkali (Cannizaro's reaction); one molecule of the aldehyde is
reduced to the corresponding alcohol and another molecule is simultaneously
oxidized to the salt of a carboxylic acid. The speed of the reaction depends on
the substituents in the aromatic ring. Two different types of aldehydes
(aromatic and aliphatic) can undergo crossing reaction to form fomaldehyde and aromatic alcohols.
2,4-Xylylaldehyde is a fragrance product. It is used
in perfumery (odur description : almond, cherry, naphthyl,
vanilla) |
SALES
SPECIFICATION |
APPEARANCE
|
clear
liquid |
ASSAY
|
98.0%
min
|
TRANSPORTATION
|
PACKING |
|
HAZARD
CLASS |
|
UN
NO. |
|
OTHER
INFORMATION |
European
Hazard Symbols: , Risk Phrases: ,
Safety Phrases: 24/25 FEMA No.: 3427 |
|