DIETHYL OXALATE

PRODUCT IDENTIFICATION

CAS NO. 95-92-1

DIETHYL OXALATE

EINECS NO. 202-464-1
FORMULA C2H5OOCCOOC2H5
MOL WT. 146.15
H.S. CODE  

TOXICITY

 
SYNONYMS Oxalic acid, Diethyl ester; Diethyl ethanedioate;
Ethanedioic acid, diethyl ester; Ethyl oxalate; Diethylester kyseliny stavelove; Diethyl ester of oxalic acid; Diethyloxalat (German); Oxalato de dietilo (Spanish); Oxalate de diéthyle (French);

SMILES

 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE Clear oily liquid
MELTING POINT -39 C
BOILING POINT 186 C
SPECIFIC GRAVITY 1.075 - 1.085
SOLUBILITY IN WATER slightly (Decomposes)
SOLVENT SOLUBILITY Soluble in miscible with alcohols, ether and other common organic solvents
pH

 

VAPOR DENSITY 5.03
AUTOIGNITION

 

NFPA RATINGS Health: 2; Flammability: 2; Reactivity: 0

REFRACTIVE INDEX

1.408 - 1.409
FLASH POINT

76 C

STABILITY Stable under ordinary conditions. Sensitive in moisture

APPLICATIONS

Diethyl Oxalate is used as a solvent for paint stripping and resins; Cleaner for polymeric residues; pigment dispersant. It is used as an intermediate to produce barbiturates (a group of ureides that act as nonselective central nervous system depressant) and dyes.
SALES SPECIFICATION

APPEARANCE

Clear liquid

ASSAY

99.0% min

WATER

0.1% max

SPECIFIC GRAVITY 1.075 - 1.085

ACIDITY

0.05% max

COLOR (APHA)

20 max

TRANSPORTATION
PACKING 200kgs in drum
HAZARD CLASS 6.1 (Packing Group: III)
UN NO.

2525

OTHER INFORMATION
European Hazard Symbols: XI, Risk Phrases: 36, Safety Phrases: 23C
GENERAL DESCRIPTION OF OXALIC ACID

Oxalic Acid (also called Ethanedioic Acid) is a colourless, crystalline, toxic organic compound belonging to the family of dicarboxylic acids; melting at 187 C; soluble in water, alcohol, and ether. It occurs in the form of its metal salts (usually calcium or potassium) in many plants. It is commercially manufactured by heating sodium formate in the presence of an alkali catalyst to form sodium oxalate, which should be converted to free oxalic acid when treated with sulfuric acid. It is also prepared by oxidizing carbohydrates with nitric acid, by heating saw dust with caustic alkalies or by fermentation of sugar solutions in the presence of certain molds. Oxalic acid is the only possible compound in which two carboxyl groups are joined directly; for this reason oxalic acid is one of the strongest acids in organic compounds. Unlike other carboxylic acids, oxalic acid (and formic acid) is readily oxidized and combine with calcium, iron, sodium, magnesium, or potassium to form less soluble salts called oxalates. Oxalic acid and oxalates are useful as reducing agents for photography, bleaching, and rust removal. They are widely used as an purifying agent in pharmaceutical industry, precipitating agent in rare-earth metal processing, bleaching agent in textile and wood industry, rust-remover for metal treatment, grinding agent, waste water treatment. acid rinse in laundries and removing scale from automobile radiators.