DIMETHYL ADIPATE

PRODUCT IDENTIFICATION
CAS NO. 627-93-0

DIMETHYL ADIPATE
EINECS NO. 211-020-6
FORMULA CH3OOC(CH2)4COOCH3
MOL WT. 174.20
H.S. CODE  

TOXICITY

  
SYNONYMS Adipic acid, dimethyl ester; Dimethyl Adipate;
Dimethyl hexanedioate; Methyl Adipate;  1,6-Dimethylhexanedioate; Dimethyl ester of hexanedioic acid;

SMILES

 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE Clear oily liquid
MELTING POINT 8 C
BOILING POINT  
SPECIFIC GRAVITY 1.055 -1.065
SOLUBILITY IN WATER Insoluble
SOLVENT SOLUBILITY Soluble in miscible with alcohols, ether and other common organic solvents
pH

 
VAPOR DENSITY 5.03
AUTOIGNITION

 
NFPA RATINGS Health: 1; Flammability: 1; Reactivity: 0

REFRACTIVE INDEX

 1.4270 - 1.4280
FLASH POINT

 
STABILITY Stable under ordinary conditions. Sensitive in moisture

APPLICATIONS
There are almost infinite esters obtained from thousands of potential starting materials. Esters are formed by removal of water from an acid and an alcohol, e.g., carboxylic acid esters, phosphoric acid esters, and sulfonic acid esters. Carboxylic acid esters are used as in a variety of direct and indirect applications. Lower chain esters are used as flavouring base materials, plasticizers, solvent carriers and coupling agents. Higher chain compounds are used as components in metalworking fluids, surfactants, lubricants, detergents, oiling agents, emulsifiers, wetting agents textile treatments and emollients, They are also used as intermediates for the manufacture of a variety of target compounds. The almost infinite esters provide a wide range of viscosity, specific gravity, vapor pressure, boiling point, and other physical and chemical properties for the proper application selections.

Adipic Acid Esters are used as low-temperature-resistant and low-viscosity plasticizer for PVC and its copolymers and cellulose esters e.g. cellulose acetate butyrates and cellulose propionates. They are used as solvent carriers or coupling agents for polyurethane and photographic films. Lower chain esters of adipic acid are used as high-boiling, biodegradable, low-toxicity solvents and antiperspirants. Longer chain esters are used as lubricants offering stable lubricity, corrosion protection, biodegradability, and performance properties at both high and low temperatures. They are used as intermediates to produce other chemical compounds.

Dimethyl Adipate is used as a solvent for paint stripping and resins; Cleaner for polymeric residues; pigment dispersant. It is used as an intermediate to produce agrochemicals and dyes.

Members of adipic acid ester or salt

Product

CAS RN
Adipoylbis(iminoethylene)bis(triethylammonium iodide) 62055-20-3
(Dibutylstannylene)bis(thioethylene) dimethyl diadipate 70969-72-1
3,3'-(Adipoyldiimino)bis(5-((2-oxo-1-pyrrolidinyl)methyl)-2,4,6-triiodobenzoic acid 51134-92-0
(2,2-Bis(hydroxymethyl)butyl) hydrogen adipate 20563-11-5
(2-Hydroxyethyl) hydrogen adipate 94109-19-0
(Adipoylbis(iminoethylene))bis((o-chlorobenzyl)diethylammonium dichloride 108021-63-2
(Dimethylstannylene)bis(thioethylene) dimethyl diadipate 70969-67-4
1-(o-(1,3-Dioxolan-2-yl)phenoxy)-3-isopropylamino-2-propanol adipate 66287-62-5
1,1'-Adipoylbisaziridine 6950-06-7
1,4-Bis(3-aminopropyl)piperazine adipate 5423-61-0
1-Decyl 6-octyl 2,2,4-trimethyladipate 68425-97-8
1-tert-Butylamino-3-(o-(1,3-dioxolan-2-yl)phenoxy)-2-propanol adipate 66287-64-7
2-(2,3-Bis(2-hydroxypropoxy)propoxy)isopropyl 2-(2-(2-hydroxypropoxy)- 3-(2-((1-oxoallyl)oxy)propoxy)propoxy) isopropyl adipate 94160-29-9
2-(3-(2-(Acryloyloxy)propoxy)-(2-(2-hydroxypropoxy))propoxy)-1-methylethyl 2-(2,3-bis(2-(acryloyloxy)propoxy)propoxy)-1-methylethyl adipate 94160-34-6
2,2-Bis(((1-oxooctyl)oxy)methyl)butyl 2-(((6-(2,2-bis(((1-oxodecyl)oxy) methyl)butoxy)-1,6-dioxohexyl)oxy) methyl)-2-(((1-oxooctyl)oxy)methyl)butyladipate 94278-18-9
2-Amino-4,5-methanoadipate 127515-30-4
2-Aminoadipic acid 542-32-5
2-Ethyl-2-(hydroxymethyl)propane-1,3-diyl adipate 94110-05-1
2-Ethylhexyl 3-methoxypropyl adipate 85670-21-9
2-Ethylhexyl hydrogen adipate 4337-65-9
2-Ethylhexyl isodecyl adipate 68052-04-0
2-Ethylhexyl phenylmethyl adipate 58394-64-2
2-Nitro-4-sulfophenyl adipate 143392-33-0
3-(2-Aminoethyl)indol-5-ol acetate adipate 19628-29-6
3-(2-Aminoethyl)indol-5-ol propionate adipate 19628-28-5
3-(5-Aminopentyl)indole adipate 31699-72-6
3-(7-Aminoheptyl)indole adipate 31699-74-8
3,3'-(1,2-Ethanediylbis(oxy))bis(1-propanamine) adipate 21697-94-9
3,3'-(Adipoyldiimino)bis(5-(acetamidomethyl)-2,4,6-triiodobenzoic acid 25901-37-5
3,3'-(Adipoyldiimino)bis(5-(butyramidomethyl)-2,4,6-triiodobenzoic acid 25903-33-7
3,3'-(Adipoyldiimino)bis(5-(propionamidomethyl)-2,4,6-triiodobenzoic acid 25901-46-6
3-Oxoadipic acid 689-31-6
6,13-Dioxa-5,14-distannaoctadecane, 5,5,14,14-tetrabutyl-7,12-dioxo- 7437-35-6
6-Decyl 1-octyl 2,2,4-trimethyladipate 67873-93-2
6-Methylheptyl 8-methylnonyl adipate 110-28-1
Acetazolamide adipate ethyl ester 111261-83-7
Acetyl di-starch adipate 63798-35-6
Adipate dianion 764-65-8
Adipate-adipic acid 134886-82-1
Adipic acid 124-04-9
Adipoylbis(iminoethylene)bis(trimethylammonium iodide) 62055-16-7
Adipoylbisphosphonic acid 139339-84-7
Adipoyldioxymethylbis(trimethylammonium iodide) 64048-56-2
Adipoyltributylplumbane 73940-91-7
Albuterol adipate diethanolate 177985-44-3
Allysine 1962-83-0
Aminotridecane adipate 35059-07-5
Benzyl butyl adipate 4121-13-5
Benzyl octyl adipate 3089-55-2
Bis((2-heptadecyl-4,5-dihydro-4-(((1-oxooctadecyl)oxy)methyl)oxazol-4-yl)methyl) adipate 94159-97-4
Bis((carboxymethyl)trimethylammonium) adipate 89713-95-1
Bis(1-butylpentyl) adipate 77916-77-9
Bis(1-isopropyl-2,2-dimethyl-3-(2-methyl-1-oxopropoxy)propyl) adipate 100208-33-1
Bis(1-methylheptyl) adipate 108-63-4
Bis(1-methylpentadecyl) adipate 58262-41-2
Bis(2-((4-(2,2-dicyanovinyl)-3-methylphenyl)ethylamino)ethyl) adipate 25857-05-0
Bis(2-(2-(2-hydroxypropoxy)-3-(2-((1-oxoallyl)oxy)propoxy)propoxy)isopropyl) adipate 94160-30-2
Bis(2-(2-butoxyethoxy)ethyl) adipate 141-17-3
Bis(2-(2-isopropyl-3-oxazolidinyl)ethyl) adipate 27325-78-6
Bis(2-(diethylamino)ethyl) adipate 16545-00-9
Bis(2-(dimethylamino)ethyl) adipate 65169-69-9
Bis(2-(ethyl(3-methylphenyl)amino)ethyl) adipate 26479-97-0
Bis(2,3-epoxypropyl) adipate 2754-17-8
Bis(2-butoxyethyl) adipate 141-18-4
Bis(2-ethoxyethyl) adipate 109-44-4
Bis(2-fluoro-2,2-dinitroethyl) adipate 35027-66-8
Bis(2-hydroxy-3-((1-oxooctadec-9-enyl)oxy)propyl) adipate 94313-92-5
Bis(2-hydroxy-3-(4-(1-(4-(2-hydroxy-3-((1-oxoallyl)oxy)propoxy)phenyl)isopropyl) phenoxy)propyl) adipate 67696-49-5
Bis(2-hydroxyethyl) 2,2,4(or 2,4,4)-trimethyladipate 84713-15-5
Bis(2-hydroxyethyl) adipate 1700-12-5
Bis(2-mercaptoethyl) adipate 10194-00-0
Bis(2-methoxyethyl) adipate 106-00-3
Bis(2-octyldodecyl) adipate 85117-94-8
Bis(3,4-epoxy-6-methylcyclohexylmethyl)adipate 1985-84-8
Bis(3,5,5-trimethylhexyl) adipate 20270-50-2
Bis(3,5-dibromosalicyl)adipate 75848-76-9
Bis(3-cyclohexen-1-ylmethyl) adipate 63905-29-3
Bis(3-cyclohexylpropyl) adipate 84731-68-0
Bis(3-methoxypropyl) adipate 85661-31-0
Bis(4-(ethenyloxy)butyl) adipate 135876-36-7
Bis(4-hydroxybutyl) adipate 20985-13-1
Bis(4-methylcyclohexyl) adipate 41544-42-7
Bis(4-nitrophenyl) adipate 32564-25-3
Bis(6-methyl-3-cyclohexenemethyl) adipate 68555-34-0
Bis(6-methylheptyl) adipate 105-96-4
Bis(7-oxabicyclo(4.1.0)hept-3-ylmethyl) adipate 3130-19-6
Bis(bicyclo(2.2.1)hept-5-en-2-ylmethyl) adipate 7359-19-5
Bis(decyl) 2,2,4(or 2,4,4)-trimethyladipate 26635-53-0
Bis(methylcyclohexyl) adipate 27479-35-2
Bis(nonylphenyl) adipate 25550-79-2
Bis(oxiranylmethyl) 2,2,4(or 2,4,4)-trimethyladipate 53445-36-6
Bis(oxiranylmethyl) 2,4,4-trimethyladipate 25677-83-2
Bis(tetrahydrofurfuryl) adipate 105-02-2
Bis(trimethylsilyl) adipate 18105-31-2
But-3-enyl hydrogen adipate 64084-45-3
Butyl decyl adipate 71850-02-7
Calcium 2,5-dimethyl-3,4-dithioxoadipate 93776-78-4
Calcium adipate 7486-40-0
Calcium adipate 22322-28-7
Calcium octadecyl adipate 94109-12-3
Ddiethylhexanedioyl dichloride 68171-35-7
Decyl hexyl adipate 22707-35-3
Decyl dodecyl trimethyladipate 93951-44-1
Decyl octyl trimethyladipate 26856-72-4
Di(2-(2-ethylbutoxy)ethyl) adipate 7790-07-0
Di(2-(hexyloxy)ethyl) adipate 110-32-7
Di(2-ethylbutyl) adipate 10022-60-3
Di-(9Z)-9-octadecenyl adipate 40677-77-8
Di-2-propenyl adipate 2998-04-1
Di-2-propynyl adipate 6900-06-7
Diammonium adipate 3385-41-9
Dianhydro-D-glucitol hydrogen adipate 93893-99-3
Dibenzyl adipate 2451-84-5
Dibutylcarbityl adipate 65520-46-9
Di-alkyl(C8-26) adipate 68989-28-6
Di-alkyl(C9-11) adipate 72379-06-7
Dicapryl adipate 105-97-5
Dicetyl adipate 26720-21-8
Dicyclohexyl adipate 849-99-0
Didecyl 2,2,4-trimethyladipate 68426-01-7
Didecyl adipate 85995-88-6
Didocosyl adipate 65540-77-4
Didodecyl adipate 3072-02-4
Diethyl 3-oxoadipate 7149-59-9
Diethyl adipate 141-28-6
Diethyl octafluoroadipate 376-50-1
Diheptadecyl adipate 26719-27-7
Diheptyl adipate 14697-48-4
Dihexadecenyl adipate 94277-08-4
Dihexyl adipate 110-33-8
Diisobutyl adipate 141-04-8
Diisocetyl adipate 57533-90-1
Diisodecyl adipate 27178-16-1
Diisohexadecyl adipate 59686-69-0
Diisononyl adipate 33703-08-1
Diisooctyl adipate 1330-86-5
Diisopentyl adipate 6624-70-0
Diisopropyl adipate 6938-94-9
Diisotridecyl adipate 26401-35-4
Dilithium adipate 18621-94-8
Dimethyl 2,2,4-trimethyladipate 29713-25-5
Dimethyl 2,2'-dibromoadipate 868-72-4
Dimethyl 2-amino-3-oxoadipate hydrochloride 6317-41-5
Dimethyl 2-methyl-5-methyleneadipate 4513-62-6
Dimethyl 3-oxoadipate 5457-44-3
Dimethyl-2-methyl adipate 19780-94-0
Dimethyladipate 627-93-0
Di-n-butyl adipate 105-99-7
Di-n-nonyl adipate 151-32-6
Dioctadecyl adipate 1119-74-0
Dioctyl 2,2,4-trimethyladipate 26635-50-7
Dioctyl 2,2,4-trimethyladipate 68975-81-5
Dioctyl 2,2,4-trimethyladipate 68425-96-7
Dioctyl adipate 103-23-1
Dioctyl hexanedioate 123-79-5
Dipentadecyl adipate 26720-20-7
Dipentyl adipate 14027-78-2
Dipotassium adipate 19147-16-1
Dipropyl adipate 106-19-4
Di-sec-butyl adipate 38447-22-2
Disodium adipate 7486-38-6
Di-tert-butyl 2,2,4-trimethyldiperoxyadipate 21850-39-5
Di-tert-butyl 2,4,4-trimethyldiperoxyadipate 21850-40-8
Ditetradecyl adipate 26720-19-4
Ditetradecyl adipate 69227-17-4
Ditridecyl adipate 16958-92-2
Divinyl adipate 4074-90-2
DL-2-Aminoadipic acid 7620-28-2
DL-alpha-Aminoadipic acid 626-71-1
Dodecyl hydrogen adipate 78194-84-0
Ethyladipoylazolamide 138080-11-2
Glyceryl adipate 26699-71-8
Hexamethylenediamine adipate 3323-53-3
Hexanedioyl dichloride 111-50-2
Iocarmate meglumine 54605-45-7
Iocarmic acid 10397-75-8
Iodipamide meglumine 3521-84-4
Iodipamide sodium 2618-26-0
Iodipamide 606-17-7
Isodecyl isooctyl adipate 31474-57-4
Isodecyl hydrogen adipate 53595-56-5
Isopropyl hydrogen adipate 52221-06-4
L-2-Aminoadipic acid 1118-90-7
Magnesium adipate 7486-39-7
Methyl adipate lithium salt 64601-11-2
Methyl vinyl adipate 2969-87-1
Mono(2-(2-(2-hydroxyethoxy)ethoxy)ethyl) adipate 64114-59-6
Mono(2-ethyl-5-hydroxyhexyl) adipate 134998-71-3
Mono(2-ethyl-5-oxohexyl) adipate 134998-72-4
Monoethyl adipate 626-86-8
Monomethyl adipate 627-91-8
n-Decyl n-octyl adipate 110-29-2
Nonylphenyl hydrogen adipate 93982-14-0
N-Tallow alkyltrimethylenediamine monoadipate 71486-98-1
N-Trifluoroacetyladriamycin-14-O-hemiadipate 80787-29-7
Octafluoroadipoyl difluoride 37881-62-2
Octyl hydrogen adipate 17961-12-5
Piperazine adipate 142-88-1
Poly(4,4'-Methylenebis(cyclohexyl isocyanate), ethylene propylene glycoladipate) 67905-79-7
Poly(adipic acid, 1,2-ethanediol, 1,2-propanediol, 1,2,3-propanetriol) 81972-42-1
Poly(adipic acid, 1,3-butanediol diacetate) 67989-20-2
Poly(adipic acid, 1,3-diisocyanatomethylbenzene, 1,2-ethanediol) 9019-92-5
Poly(adipic acid, 1,3-diisocyanatomethylbenzene, 1,2-ethanediol, 1,2-propanediol) 9063-78-9
Poly(adipic acid, 1,3-diisocyanatomethylbenzene, 2,2-dimethyl-1,3-propanediol, 1,6-hexanediol , 3-hydroxy-2-(hydroxymethyl)-2-methylpropanoic acid) 67952-86-7
Poly(adipic acid, 1,3-diisocyanatomethylbenzene, 2,2'-oxybis(ethanol)) 9017-08-7
Poly(adipic acid, 1,3-diisocyanatomethylbenzene, methyloxirane, oxirane) 69331-29-9
Poly(adipic acid, ethylene glycol, diphenylmethanediisocyanate) 9042-80-2
Poly(butylene adipate) 52012-76-7
Poly(ethylene propylene glycol adipate, 4,4'-methylenebis(cyclohexyl isocyanate) ) 27084-91-9
Poly(oxypropylene) glycerol adipate 68439-20-3
Poly(propylene adipate) 25101-03-5
Polybutilate 24936-97-8
Polypropyleneglycoladipate 42615-42-9
Potassium sodium adipate 19584-53-3
Serotonin adipinate 13425-34-8
Serotonin adipinate 16031-83-7
Siomycin A hemiadipate-II sodium heptahydrate 79300-38-2
Sodium hydrogen adipate 18996-34-4
Spiramycin adipate 68880-55-7
Strontium adipate 85169-08-0
Tetradecyl hydrogen adipate 93777-47-0
Tetrahydrofurfuryl hydrogen adipate 93966-45-1
Vinyl hydrogen adipate 5238-38-0
Zinc adipate 3446-35-3
SALES SPECIFICATION

APPEARANCE

 Clear liquid

ASSAY

99.0% min

WATER

0.1% max
SPECIFIC GRAVITY 1.055 - 1.065

ACIDITY

0.02% max

COLOR (APHA)

20 max
TRANSPORTATION
PACKING 200kgs in drum
HAZARD CLASS Not regulated
UN NO.

 
OTHER INFORMATION
European Hazard Symbols: n/a, Risk Phrases: n/a, Safety Phrases: 24/25-28A-37-45

GENERAL DESCRIPTION OF  ADIPIC ACID
Adipic Acid (also called hexanedioic acid) is a white, crystalline compound of  C6 straight-chain dicarboxylic acid; slightly soluble in water and soluble in alcohol and acetone. Almost all of the commercial adipic acid is produced from cyclohexane through two sequent oxidation processes. The first oxidation is the reacting of cyclohexane with oxygen in the presents of cobalt or manganese catalysts at a temperature of 150 - 160 C, which produce cyclohexanol and cyclohexanone. Then, the intermediates are further reacted with nitric acid and air with a catalyst (copper or vanadium) or without nitric acid. Cyclohexane can be prepared by the hydrogenation of benzene. There are other ways such as the reactions using phenol, butadiene, and various fats as the starting material. Adipic acid consumption is linked almost 90% to nylon production by the polycondensation with hexamethylenediamine. Nylon, having a protein-like structure, is further processed into fibers for applications in carpeting, automobile tire cord  and clothing. Adipic acid is used in manufacturing plasticizers and lubricants components. It is used in making polyester polyols for polyurethane systems. Food grade adipic acid is used as gelling aid, acidulant, leavening and buffering agent. Adipic acid has two carboxylic acid, -COOH, groups, which can yield two kinds of salts. Its derivatives, acyl halides, anhydrides, esters, amides and nitriles, are used in making target products such as flavoring agents, internal plasticizers, pesticides, dyes, textile treatment agents, fungicides, and pharmaceuticals through further reactions of substitution, catalytic reduction, metal hydride reduction, diborane reduction, keto formation with organometallic reagents, electrophile bonding at oxygen, and condensation.