CAS
NO. |
616-38-6 |
|
EINECS
NO. |
210-478-4 |
FORMULA |
(CH3)2CO3 |
MOL
WT. |
90.08 |
H.S.
CODE |
|
TOXICITY
|
|
SYNONYMS |
DMC;
Methyl carbonate; Carbonic acid dimethyl ester; |
SMILES
|
|
CLASSIFICATION
|
|
PHYSICAL
AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
clear
liquid |
MELTING
POINT |
2
- 4 C |
BOILING
POINT |
90
C
|
SPECIFIC
GRAVITY |
1.069
- 1.073 |
SOLUBILITY
IN WATER |
Insoluble |
pH |
|
VAPOR
DENSITY |
3.1 |
AUTOIGNITION |
|
NFPA
RATINGS |
Health:
3; Flammability: 3; Reactivity: 0 |
REFRACTIVE
INDEX |
|
FLASH
POINT |
18
C
|
STABILITY |
Stable
under ordinary conditions
|
APPLICATIONS
|
Dimethyl
Carbonate is a solvent of both extraction and reaction
used in many industries; pharmaceuticals; agrochemicals;
hydrocarbon refinery; paint and coatings and
fragrances;
It is used as a methylation and carbonylation agent
in organic synthesis. It can be used as fuel
and lube additive. |
SALES
SPECIFICATION |
APPEARANCE
|
clear
liquid |
CONTENT |
99.0%
min
|
WATER
|
0.1%
max
|
FREE
ACID
|
0.2%
max
|
NON-VOLATILES
|
0.2%
max
|
TRANSPORTATION |
PACKING |
200kgs
in drum |
HAZARD
CLASS |
3
(Packing Group: II) |
UN
NO. |
1161 |
OTHER
INFORMATION |
Hazard Symbols: F, Risk Phrases: 11, Safety Phrases:
9-16-29-33 |
GENERAL
DESCRIPTION OF CARBONIC ACID |
Carbonic acid (H2CO3) is a carbon-containing dibasic acid which has two acidic
hydrogen atoms in the same molecule. The other common example of dibasic acid is
sulfuric acid (H2SO4). Carbonic acid is formed in solution when its anhydride
(carbon dioxide) is dissolved in water, existing only in equilibrium. The
equilibrium is important for organisms to perform certain vital functions. The
body fluids must maintain a constant pH. For example, blood must maintain a pH
of close to 7.4 in order to carry oxygen from the lungs to cells. Carbonic acid
has two acidic hydrogens and can lose one or two protons. The presence of pure
carbonic acid is not possible as even a single molecule of water causes the
carbonic acid to revert to carbon dioxide and water fairly quickly. Pure
carbonic acid can be found if there is no water absolutely. Carbonic acid itself
is a stronger acid than acetic acid or formic acid due to the influence of the
electronegative oxygen substituent. Considering the equilibrium constant,
however, the majority of the carbon dioxide is not converted into carbonic acid
and so such solutions are fairly weak. Carbonic acid forms two series of salts
when combined with positive or basic atoms or radicals; the hydrogencarbonate
which contain the hydrogencarbonate ion HCO3- formed when the first
proton is removed and the carbonate which contain the carbonate ion, CO32-
formed when the second proton is removed. Hydrogencarbonates are also called
bicarbonate or acid carbonate. Bicarbonates are formed under the presence of
excess acid, while carbonates are formed when equivalent amounts of acid and
base react. Most carbonic acid salts which are formed by reacting an inorganic
base are the most basic industrial chemicals. |