GRIGNARD REAGENTS
REAGENT |
CAS # |
FORMULA |
MOL WT. |
SOLUBILITY & SOLVENT |
| ||||
◆ ALKANE GRIGNARDS ◆ | ||||
|
||||
Methylmagnesium Chloride |
676-58-4 |
CH3MgCl |
74.79 |
3.0 M in Tetrahydrofuran |
Ethylmagnesium Chloride |
2386-64-3 |
CH3CH2MgCl |
88.82 |
2.0 M in Tetrahydrofuran |
Ethylmagnesium Chloride |
2386-64-3 |
CH3CH2MgCl |
88.82 |
2.0 M in Diethyl Ether |
Propylmagnesium Chloride |
2234-82-4 |
CH3CH2CH2MgCl |
102.85 |
2.0 M in Diethyl Ether |
Isopropylmagnesium Chloride |
1068-55-9 |
(CH3)2CHMgCl |
102.85 |
2.0 M in Diethyl Ether |
Isopropylmagnesium Chloride |
1068-55-9 |
(CH3)2CHMgCl |
102.85 |
2.0 M in Tetrahydrofuran |
Isopropylmagnesium Chloride |
1068-55-9 |
(CH3)2CHMgCl |
102.85 |
1.4 M in butyl diglyme |
Isobutylmagnesium Chloride |
5674-02-2 |
(CH3)2CHCH2MgCl |
116.87 |
2.0 M in Tetrahydrofuran |
sec-Butylmagnesium Chloride |
15366-08-2 |
CH3CH2CH(CH3)MgCl |
116.87 |
2.0 M in Diethyl Ether |
Butylmagnesium Chloride |
693-04-9 |
CH3(CH2)3MgCl |
116.87 |
2.0 M in Tetrahydrofuran |
Isobutylmagnesium Chloride |
5674-02-2 |
(CH3)2CHCH2MgCl |
116.87 |
2.0 M in Diethyl Ether |
Butylmagnesium Chloride |
693-04-9 |
CH3(CH2)3MgCl |
116.87 |
1.45 M in butyl diglyme |
tert-Butylmagnesium Chloride |
677-22-5 |
(CH3)3CMgCl |
116.87 |
2.0 M in Diethyl Ether |
tert-Butylmagnesium Chloride |
677-22-5 |
(CH3)3CMgCl |
116.87 |
1.0 M in Tetrahydrofuran |
Butylmagnesium Chloride |
693-04-9 |
CH3(CH2)3MgCl |
116.87 |
2.0 M in Diethyl Ether |
Methylmagnesium Bromide |
75-16-1 |
CH3MgBr |
119.24 |
1.0 M in butyl ether |
Methylmagnesium Bromide |
75-16-1 |
CH3MgBr |
119.24 |
3.0 M in Diethyl Ether |
Cyclopentylmagnesium Chloride |
32916-51-1 |
C5H9ClMg |
128.88 |
2.0 M in Diethyl Ether |
Neopentylmagnesium Chloride |
13132-23-5 |
(CH3)3CCH2MgCl |
130.90 |
1.0 M in Diethyl Ether |
Pentylmagnesium Chloride |
6393-56-2 |
CH3(CH2)4MgCl |
130.90 |
2.0 M in Tetrahydrofuran |
1,1-Dimethylpropylmagnesium Chloride |
28276-08-6 |
C2H5C(CH3)2MgCl |
130.90 |
1.0 M in Diethyl Ether |
Ethylmagnesium Bromide |
925-90-6 |
CH3CH2MgBr |
133.27 |
3.0 M in Diethyl Ether |
Ethylmagnesium Bromide |
925-90-6 |
CH3CH2MgBr |
133.27 |
1.0 M in tert-butyl methyl ether |
Ethylmagnesium Bromide |
925-90-6 |
CH3CH2MgBr |
133.27 |
1.0 M in Tetrahydrofuran |
Dibutylmagnesium |
1191-47-5 |
[CH3(CH2)3]2Mg |
138.53 |
1.0 M in heptane |
Cyclohexylmagnesium Chloride |
931-51-1 |
C6H11ClMg |
142.91 |
2.0 M in Diethyl Ether |
Cyclopropylmagnesium Bromide |
23719-80-4 |
C3H5BrMg |
145.28 |
0.5 M in Tetrahydrofuran |
(Trimethylsilyl)methylmagnesium Chloride |
13170-43-9 |
(CH3)3SiCH2MgCl |
147.98 |
1.0 M in Diethyl Ether |
Butylmagnesium Bromide |
693-03-8 |
CH3(CH2)3MgBr |
161.32 |
3.0 M In Diethyl Ether |
Isobutylmagnesium Bromide |
926-62-5 |
(CH3)2CHCH2MgBr |
161.32 |
2.0 M in Diethyl Ether |
Butylmagnesium Bromide |
693-03-8 |
CH3(CH2)3MgBr |
161.32 |
1.0 M In Tetrahydrofuran |
Methylmagnesium iodide |
917-64-6 |
CH3MgI |
166.24 |
3.0 M in Diethyl Ether |
Trideutero-methylmagnesium iodide |
41251-37-0 |
CD3MgI |
169.26 |
1.0 M in Diethyl Ether |
Magnesium Tert-butoxide |
32149-57-8 |
C8H18MgO2 |
170.53 |
|
Octylmagnesium Chloride |
38841-98-4 |
C8H17MgCl |
172.98 |
2.0 M in Tetrahydrofuran |
Cyclopentylmagnesium Bromide |
33240-34-5 |
C5H9MgBr |
173.33 |
2.0 M in Diethyl Ether |
Pentylmagnesium Bromide |
693-25-4 |
C5H11MgBr |
175.35 |
2.0 M in Diethyl Ether |
Butylmagnesium diisopropylamide |
138858-13-6 |
[(CH3)2CH]2NMg(CH2)3CH3 |
181.60 |
1.0 M in Tetrahydrofuran |
Hexylmagnesium Bromide |
3761-92-0 |
CH3(CH2)5MgBr |
189.38 |
2.0 M in Diethyl Ether |
(1,3-Dioxolan-2-ylmethyl)magnesium Bromide |
180675-22-3 |
C4H7BrMgO2 |
191.31 |
0.5 M in Tetrahydrofuran |
Heptylmagnesium Bromide |
13125-66-1 |
CH3(CH2)6MgBr |
203.40 |
1.0 M in Diethyl Ether |
Octylmagnesium Bromide |
17049-49-9 |
CH3(CH2)7MgBr |
217.43 |
2.0 M in Diethyl Ether |
(2-Ethylhexyl)magnesium Bromide |
90224-21-8 |
C8H17BrMg |
217.43 |
1.0 M in in Diethyl Ether |
(1,3-Dioxan-2-ylethyl)magnesium Bromide |
480438-44-6 |
C6H11BrMgO2 |
219.36 |
0.5 M in Tetrahydrofuran |
Nonylmagnesium Bromide |
39691-62-8 |
CH3(CH2)8MgBr |
231.46 |
1.0 M in Diethyl Ether |
Decylmagnesium Bromide |
17049-50-2 |
CH3(CH2)9MgBr |
245.48 |
1.0 M in Diethyl Ether |
Tetradecylmagnesium Chloride |
110220-87-6 |
CH3(CH2)13MgCl |
257.14 |
1.0 M in Tetrahydrofuran |
Dodecylmagnesium Bromide |
15890-72-9 |
CH3(CH2)11MgBr |
273.54 |
1.0 M in Diethyl Ether |
Pentane-1,5-di(magnesium Bromide) |
23708-48-7 |
BrMg(CH2)5MgBr |
278.55 |
0.5 M in Tetrahydrofuran |
Octadecylmagnesium Chloride |
116980-66-6 |
CH3(CH2)17MgCl |
313.24 |
0.5 M in Tetrahydrofuran |
Pentadecylmagnesium Bromide |
78887-70-4 |
CH3(CH2)14MgBr |
315.62 |
0.5 M in Diethyl Ether |
| ||||
◆ ALKENE GRIGNARDS ◆ | ||||
|
|
|
|
|
Vinylmagnesium Chloride |
3536-96-7 |
CH2=CHMgCl |
86.80 |
1.6 M in Tetrahydrofuran |
Allylmagnesium Chloride |
2622-05-1 |
CH2=CHCH2MgCl |
100.83 |
2.0 M in Tetrahydrofuran |
1-Methyl-2-propenylmagnesium Chloride |
21969-32-4 |
H2C=CHCH(CH3)MgCl |
114.86 |
0.5 M in Tetrahydrofuran |
2-Methylallylmagnesium Chloride |
5674-01-1 |
H2C=C(CH3)CH2MgCl |
114.86 |
0.5 M in Tetrahydrofuran |
2-Butenylmagnesium Chloride |
22649-70-3 |
CH3CH=CHCH2MgCl |
114.86 |
0.5 M in Tetrahydrofuran |
Vinylmagnesium Bromide |
1826-67-1 |
CH2=CHMgBr |
131.25 |
1.0 M in Tetrahydrofuran |
1-Propenylmagnesium Bromide |
14092-04-7 |
CH3CH=CHMgBr |
145.28 |
0.5 M in Tetrahydrofuran |
Allylmagnesium Bromide |
1730-25-2 |
CH2=CHCH2MgBr |
145.28 |
1.0 M in Diethyl Ether |
Isopropenylmagnesium Bromide |
13291-18-4 |
CH2=C(CH3)MgBr |
145.28 |
0.5 M in Tetrahydrofuran |
3-Butenylmagnesium Bromide |
7103-09-5 |
H2C=CHCH2CH2MgBr |
159.31 |
0.5 M in Tetrahydrofuran |
1-Methyl-1-propenylmagnesium Bromide |
85676-85-3 |
CH3CH=C(CH3)MgBr |
159.31 |
0.5 M in Tetrahydrofuran |
2-Methyl-1-propenylmagnesium Bromide |
38614-36-7 |
CH3CH=C(CH3)MgBr |
159.31 |
0.5 M in Tetrahydrofuran |
◆ ALKYNE GRIGNARDS ◆ | ||||
Ethynylmagnesium Bromide |
4301-14-8 |
HC≡CMgBr |
129.24 |
0.5 M in Tetrahydrofuran |
Ethynylmagnesium Chloride |
65032-27-1 |
CH≡CMgCl |
84.79 |
0.5 M in Tetrahydrofuran |
1-Propynylmagnesium Bromide |
16466-97-0 |
CH3C≡CMgBr |
143.26 |
0.5 M in Tetrahydrofuran |
Phenylethynylmagnesium Bromide |
6738-06-3 |
C6H5C≡CMgBr |
205.33 |
1.0 M in Tetrahydrofuran |
◆ ARYL GRIGNARDS ◆ | ||||
2-Methoxyphenylmagnesium Bromide |
16750-63-3 |
CH3OC6H4MgBr |
|
1.0 M in Tetrahydrofuran |
Phenylmagnesium Chloride |
100-59-4 |
C6H5MgCl |
136.86 |
2.0 M in Tetrahydrofuran |
2-Methylphenylmagnesium Chloride |
33872-80-9 |
CH3C6H4MgCl |
150.89 |
1.0 M in Tetrahydrofuran |
m-Tolylmagnesium Chloride |
121905-60-0 |
CH3C6H4MgCl |
150.89 |
1.0 M in Tetrahydrofuran |
Benzylmagnesium Chloride |
6921-34-2 |
C6H5CH2MgCl |
150.89 |
1.0 M in Diethyl Ether |
Benzylmagnesium Chloride |
6921-34-2 |
C6H5CH2MgCl |
150.89 |
2.0 M in Tetrahydrofuran |
Phenethylmagnesium Chloride |
90878-19-6 |
C6H5CH2CH2MgCl |
164.92 |
1.0 M in Tetrahydrofuran |
4-Methylbenzylmagnesium Chloride |
29875-07-8 |
H3CC6H4CH2MgCl |
164.92 |
|
3-Methylbenzylmagnesium Chloride |
29875-06-7 |
H3CC6H4CH2MgCl |
164.92 |
|
2-Methylbenzylmagnesium Chloride |
29875-05-6 |
H3CC6H4CH2MgCl |
164.92 |
0.25 M in Tetrahydrofuran |
3,4-Dimethylphenylmagnesium Chloride |
102928-12-1 |
(CH3)2C6H3MgCl |
164.92 |
0.5 M in Tetrahydrofuran |
3-Fluoro-2-methylphenylmagnesium Chloride |
480424-74-6 |
C6H3FCH3MgCl |
168.88 |
|
4-Fluorobenzylmagnesium Chloride |
1643-73-8 |
FC6H4CH2MgCl |
168.88 |
|
4-Methoxybenzylmagnesium Chloride |
38769-92-5 |
CH3OC6H4CH2MgCl |
180.91 |
0.25 M in Tetrahydrofuran |
2-Methoxybenzylmagnesium Chloride |
480438-46-8 |
CH3OC6H4CH2MgCl |
180.91 |
0.25 M in Tetrahydrofuran |
3-Methoxybenzylmagnesium Chloride |
26905-40-8 |
CH3OC6H4CH2MgCl |
180.91 |
0.25 M in Tetrahydrofuran |
Phenylmagnesium Bromide |
100-58-3 |
C6H5MgBr |
181.31 |
3.0 M in Diethyl Ether |
Phenylmagnesium Bromide |
100-58-3 |
C6H5MgBr |
181.31 |
1.0 M in Tetrahydrofuran |
2-Methyl-2-phenylpropylmagnesium Chloride |
35293-35-7 |
C6H5C(CH3)2CH2MgCl |
192.97 |
0.5 M in Diethyl Ether |
4-Methoxyphenethylmagnesium Chloride |
211115-05-8 |
H3COC6H4CH2CH2MgCl |
194.94 |
0.5 M in Tetrahydrofuran |
o-Tolylmagnesium Bromide |
932-31-0 |
CH3C6H4MgBr |
195.34 |
2.0 M in Diethyl Ether |
p-Tolylmagnesium Bromide |
4294-57-9 |
CH3C6H4MgBr |
195.34 |
1.0 M in Tetrahydrofuran |
3-Fluorophenylmagnesium Bromide |
17318-03-5 |
FC6H4MgBr |
199.30 |
1.0 M in Tetrahydrofuran |
4-Fluorophenylmagnesium Bromide |
352-13-6 |
FC6H4MgBr |
199.30 |
1.0 M in Tetrahydrofuran |
4-Fluorophenylmagnesium Bromide |
352-13-6 |
FC6H4MgBr |
199.30 |
2.0 M in Diethyl Ether |
4-Ethylphenylmagnesium Bromide |
22873-28-5 |
C2H5C6H4MgBr |
209.37 |
0.5 M in Tetrahydrofuran |
2,3-Dimethylphenylmagnesium Bromide |
134640-85-0 |
(CH3)2C6H3MgBr |
209.37 |
|
2,4-Dimethylphenylmagnesium Bromide |
34589-46-3 |
(CH3)2C6H3MgBr |
209.37 |
0.5 M in Tetrahydrofuran |
2,5-Dimethylphenylmagnesium Bromide |
30897-86-0 |
(CH3)2C6H3MgBr |
209.37 |
|
2,6-Dimethylphenylmagnesium Bromide |
21450-64-6 |
(CH3)2C6H3MgBr |
209.37 |
1.0 M in Tetrahydrofuran |
3,5-Dimethylphenylmagnesium Bromide |
34696-73-6 |
(CH3)2C6H3MgBr |
209.37 |
0.5 M in Tetrahydrofuran |
3,5-Dimethoxybenzylmagnesium Chloride |
135808-66-1 |
C6H3(OCH3)2CH2MgCl |
210.94 |
|
3-Methoxyphenylmagnesium Bromide |
36282-40-3 |
CH3OC6H4MgBr |
211.34 |
1.0 M in Tetrahydrofuran |
5-Fluoro-2-methylphenylmagnesium Bromide |
186496-59-3 |
FC6H3(CH3)MgBr |
213.33 |
0.5 M in Tetrahydrofuran |
4-Fluoro-3-methylphenylmagnesium Bromide |
82297-89-0 |
FC6H3(CH3)MgBr |
213.33 |
1.0 M in Tetrahydrofuran |
3-Fluoro-4-methylphenylmagnesium Bromide |
185077-02-5 |
FC6H3(CH3)MgBr |
213.33 |
0.5 M in Tetrahydrofuran |
4-Fluoro-2-methylphenylmagnesium Bromide |
30897-90-6 |
FC6H3(CH3)MgBr |
213.33 |
0.5 M in Tetrahydrofuran |
4-Chlorophenylmagnesium Bromide |
873-77-8 |
ClC6H4MgBr |
215.76 |
1.0 M in Diethyl Ether |
3-Chlorophenylmagnesium Bromide |
36229-42-2 |
C6H4BrClMg |
215.76 |
|
3,5-Difluorophenylmagnesium Bromide |
62351-47-7 |
F2C6H3MgBr |
217.29 |
0.5 M in Tetrahydrofuran |
3,4-Difluorophenylmagnesium Bromide |
90897-92-0 |
F2C6H3MgBr |
217.29 |
0.5 M in Tetrahydrofuran |
2,4,6-Trimethylphenylmagnesium Bromide |
2633-66-1 |
(CH3)3C6H2MgBr |
223.39 |
1.0 M in Diethyl Ether |
4-n-Propylphenylmagnesium Bromide |
87942-08-3 |
C6H4CH2CH2CH3MgBr |
223.39 |
|
3,5-Dimethyl-4-methoxyphenylmagnesium Bromide |
185416-17-5 |
C6H2CH3CH3OCH3MgBr |
223.39 |
|
2,4,6-Trimethylphenylmagnesium Bromide |
2633-66-1 |
(CH3)3C6H2MgBr |
223.39 |
1.0 M in Tetrahydrofuran |
4-(N,N-Dimethyl)aniline magnesium Bromide |
7353-91-5 |
(CH3)2NC6H4MgBr |
224.38 |
0.5 M in Tetrahydrofuran |
3,4-(Methylenedioxy)phenylmagnesium Bromide |
17680-04-5 |
C7H5BrMgO2 |
225.32 |
1.0 M in toluene/Tetrahydrofuran (50:50) |
4-Methoxy-2-methylphenylmagnesium Bromide |
148706-30-3 |
CH3OC6H3(CH3)MgBr |
225.37 |
0.5 M in Tetrahydrofuran |
3-Fluoro-6-methoxyphenylmagnesium Bromide |
188132-02-7 |
FC6H3(OCH3)MgBr |
229.33 |
0.5 M in Tetrahydrofuran |
3-Fluoro-4-methoxyphenylmagnesium Bromide |
112780-67-3 |
FC6H3(OCH3)MgBr |
229.33 |
|
4-Chloro-2-methylphenylmagnesium Bromide |
480438-47-9 |
ClC6H3(CH3)MgBr |
229.78 |
|
2-Naphthylmagnesium Bromide |
21473-01-8 |
C10H7BrMg |
231.37 |
|
1-Naphthylmagnesium Bromide |
703-55-9 |
C10H7BrMg |
231.37 |
0.25 M in Tetrahydrofuran |
3-Chloro-4-fluorophenylmagnesium Bromide |
413589-34-1 |
C6H3BrClFMg |
233.75 |
0.5 M in Tetrahydrofuran |
3-Chloro-5-fluorophenylmagnesium Bromide |
480438-50-4 |
ClC6H3(F)MgBr |
233.75 |
0.5 M in Tetrahydrofuran |
4-Chloro-3-fluorophenylmagnesium Bromide |
170793-00-7 |
ClC6H3(F)MgBr |
233.75 |
0.5 M in Tetrahydrofuran |
3,4,5-Trifluorophenylmagnesium Bromide |
156006-28-9 |
F3C6H2MgBr |
235.28 |
0.3 M in Tetrahydrofuran |
4-Butylphenylmagnesium Bromide |
185416-14-2 |
CH3(CH2)3C6H4MgBr |
237.42 |
0.5 M in Tetrhydrofuran |
4-tert-Butylphenylmagnesium Bromide |
63488-10-8 |
(CH3)3CC6H4MgBr |
237.42 |
2.0 M in Diethyl Ether |
2,4-Dimethoxyphenylmagnesium Bromide |
138109-49-6 |
(CH3O)2C6H3MgBr |
241.36 |
0.5 M in Tetrahydrofuran |
2,5-Dimethoxyphenylmagnesium Bromide |
62890-98-6 |
(CH3O)2C6H3MgBr |
241.36 |
0.5 M in Tetrahydrofuran |
3,4-Dimethoxyphenylmagnesium Bromide |
89980-69-8 |
(CH3O)2C6H3MgBr |
241.36 |
0.5 M in Tetrahydrofuran |
2-Methyl-1-napthylmagnesium Bromide |
21450-90-8 |
C10H6CH3MgBr |
245.40 |
|
4-Methyl-1-naphthylmagnesium Bromide |
115913-58-1 |
C10H6CH3MgBr |
245.40 |
|
3,4-Dichlorophenylmagnesium Bromide |
79175-35-2 |
Cl2C6H3MgBr |
250.20 |
0.5 M in Tetrahydrofuran |
3,5-Dichlorophenylmagnesium Bromide |
82297-90-3 |
Cl2C6H3MgBr |
250.20 |
0.5 M in Tetrahydrofuran |
4-Biphenylmagnesium Bromide |
3315-91-1 |
C6H5C6H4MgBr |
257.41 |
0.5 M in Tetrahydrofuran |
(3-(1-Pyrrolidinylmethyl)phenyl)magnesium Bromide |
480424-79-1 |
C6H4CH2NC4H8MgBr |
264.44 |
|
(4-(1-Pyrrolidinylmethyl)phenyl)magnesium Bromide |
480424-78-0 |
C6H4CH2NC4H8MgBr |
264.44 |
0.25 M in Tetrahydrofuran |
(2-(1-Pyrrolidinylmethyl)phenyl)magnesium Bromide |
480424-80-4 |
C6H4CH2NC4H8MgBr |
264.44 |
|
Pentafluorophenylmagnesium Bromide |
879-05-0 |
C6F5MgBr |
271.27 |
0.5 M in Diethyl Ether |
4-Phenoxyphenylmagnesium Bromide |
21473-02-9 |
C6H5OC6H4MgBr |
273.41 |
0.5 M in Tetrahydrofuran |
3-Bromobenzylmagnesium Bromide |
107549-22-4 |
BrC6H4CH2MgBr |
274.24 |
0.25 M in Diethyl Ether |
2-Bromobenzylmagnesium Bromide |
56812-60-3 |
BrC6H4CH2MgBr |
274.24 |
0.25 M in Diethyl Ether |
[2-(1-Piperidinylmethyl)phenyl]magnesium Bromide |
480424-81-5 |
C6H4CH2NC5H10MgBr |
278.47 |
0.25 M in Tetrahydrofuran |
(4-(1-Piperidinylmethyl)phenyl)magnesium Bromide |
480424-83-7 |
C6H4CH2NC5H10MgBr |
278.47 |
0.25 M in Tetrahydrofuran |
[3-(1-Piperidinylmethyl)phenyl]magnesium Bromide |
480424-82-6 |
C6H4CH2NC5H10MgBr |
278.47 |
0.25 M in Tetrahydrofuran |
[2-(4-Morpholinylmethyl)phenyl]magnesium Bromide |
480424-77-9 |
C11H14BrMgNO |
280.44 |
|
(3-(4-Morpholinylmethyl)phenyl)magnesium Bromide |
480424-76-8 |
C6H4CH2NOC4H8MgBr |
280.44 |
0.25 M in Tetrahydrofuran |
4-(2-Tetrahydro-2H-pyranoxy)phenylmagnesium Bromide |
36637-44-2 |
C11H13BrMgO2 |
281.43 |
0.5 M in Tetrahydrofuran |
9-Phenanthrylmagnesium Bromide |
71112-64-6 |
C14H9BrMg |
281.43 |
|
3-[Bis(trimethylsilyl)amino]phenylmagnesium Chloride |
174484-84-5 |
[(CH3)3Si]2NC6H4MgCl |
296.24 |
1.0 M in Tetrahydrofuran |
| ||||
◆ THIO GRIGNARDS ◆ | ||||
|
||||
Thiophen-2-yl-magnesium Bromide |
5713-61-1 |
C4H3BrMgS |
187.34 |
1.0 M in Tetrahydrofuran |
3-Methyl-2-thienylmagnesium Bromide |
95184-07-9 |
C5H5BrMgS |
201.37 |
0.5 M in Tetrahydrofuran |
5-Chloro-2-thienylmagnesium Bromide |
111762-30-2 |
C4H2BrClMgS |
221.79 |
|
4-Thioanisolemagnesium Bromide |
18620-04-7 |
H3CSC6H4MgBr |
227.40 |
0.5 M in Tetrahydrofuran |
3-Thienylmagnesium iodide |
172035-86-8 |
C4H3IMgS |
234.34 |
0.5 M in Tetrahydrofuran |