GRIGNARD REAGENTS

REAGENT

CAS #

FORMULA

MOL WT.

SOLUBILITY & SOLVENT

 

ALKANE GRIGNARDS

 

Methylmagnesium Chloride

676-58-4

CH3MgCl

74.79

3.0 M in Tetrahydrofuran

Ethylmagnesium Chloride

2386-64-3

CH3CH2MgCl

88.82

2.0 M in Tetrahydrofuran

Ethylmagnesium Chloride

2386-64-3

CH3CH2MgCl

88.82

2.0 M in Diethyl Ether

Propylmagnesium Chloride

2234-82-4

CH3CH2CH2MgCl

102.85

2.0 M in Diethyl Ether

Isopropylmagnesium Chloride

1068-55-9

(CH3)2CHMgCl

102.85

2.0 M in Diethyl Ether

Isopropylmagnesium Chloride

1068-55-9

(CH3)2CHMgCl

102.85

2.0 M in Tetrahydrofuran

Isopropylmagnesium Chloride

1068-55-9

(CH3)2CHMgCl

102.85

1.4 M in butyl diglyme

Isobutylmagnesium Chloride

5674-02-2

(CH3)2CHCH2MgCl

116.87

2.0 M in Tetrahydrofuran

sec-Butylmagnesium Chloride

15366-08-2

CH3CH2CH(CH3)MgCl

116.87

2.0 M in Diethyl Ether

Butylmagnesium Chloride

693-04-9

CH3(CH2)3MgCl

116.87

2.0 M in Tetrahydrofuran

Isobutylmagnesium Chloride

5674-02-2

(CH3)2CHCH2MgCl

116.87

2.0 M in Diethyl Ether

Butylmagnesium Chloride

693-04-9

CH3(CH2)3MgCl

116.87

1.45 M in butyl diglyme

tert-Butylmagnesium Chloride

677-22-5

(CH3)3CMgCl

116.87

2.0 M in Diethyl Ether

tert-Butylmagnesium Chloride

677-22-5

(CH3)3CMgCl

116.87

1.0 M in Tetrahydrofuran

Butylmagnesium Chloride

693-04-9

CH3(CH2)3MgCl

116.87

2.0 M in Diethyl Ether

Methylmagnesium Bromide

75-16-1

CH3MgBr

119.24

1.0 M in butyl ether

Methylmagnesium Bromide

75-16-1

CH3MgBr

119.24

3.0 M in Diethyl Ether

Cyclopentylmagnesium Chloride

32916-51-1

C5H9ClMg

128.88

2.0 M in Diethyl Ether

Neopentylmagnesium Chloride

13132-23-5

(CH3)3CCH2MgCl

130.90

1.0 M in Diethyl Ether

Pentylmagnesium Chloride

6393-56-2

CH3(CH2)4MgCl

130.90

2.0 M in Tetrahydrofuran

1,1-Dimethylpropylmagnesium Chloride

28276-08-6

C2H5C(CH3)2MgCl

130.90

1.0 M in Diethyl Ether

Ethylmagnesium Bromide

925-90-6

CH3CH2MgBr

133.27

3.0 M in Diethyl Ether

Ethylmagnesium Bromide

925-90-6

CH3CH2MgBr

133.27

1.0 M in tert-butyl methyl ether

Ethylmagnesium Bromide

925-90-6

CH3CH2MgBr

133.27

1.0 M in Tetrahydrofuran

Dibutylmagnesium

1191-47-5

[CH3(CH2)3]2Mg

138.53

1.0 M in heptane

Cyclohexylmagnesium Chloride

931-51-1

C6H11ClMg

142.91

2.0 M in Diethyl Ether

Cyclopropylmagnesium Bromide

23719-80-4

C3H5BrMg

145.28

0.5 M in Tetrahydrofuran

(Trimethylsilyl)methylmagnesium Chloride

13170-43-9

(CH3)3SiCH2MgCl

147.98

1.0 M in Diethyl Ether

Butylmagnesium Bromide

693-03-8

CH3(CH2)3MgBr

161.32

3.0 M In Diethyl Ether

Isobutylmagnesium Bromide

926-62-5

(CH3)2CHCH2MgBr

161.32

2.0 M in Diethyl Ether

Butylmagnesium Bromide

693-03-8

CH3(CH2)3MgBr

161.32

1.0 M In Tetrahydrofuran

Methylmagnesium iodide

917-64-6

CH3MgI

166.24

3.0 M in Diethyl Ether

Trideutero-methylmagnesium iodide

41251-37-0

CD3MgI

169.26

1.0 M in Diethyl Ether

Magnesium Tert-butoxide

32149-57-8

C8H18MgO2

170.53

 

Octylmagnesium Chloride

38841-98-4

C8H17MgCl

172.98

2.0 M in Tetrahydrofuran

Cyclopentylmagnesium Bromide

33240-34-5

C5H9MgBr

173.33

2.0 M in Diethyl Ether

Pentylmagnesium Bromide

693-25-4

C5H11MgBr

175.35

2.0 M in Diethyl Ether

Butylmagnesium diisopropylamide

138858-13-6

[(CH3)2CH]2NMg(CH2)3CH3

181.60

1.0 M in Tetrahydrofuran

Hexylmagnesium Bromide

3761-92-0

CH3(CH2)5MgBr

189.38

2.0 M in Diethyl Ether

(1,3-Dioxolan-2-ylmethyl)magnesium Bromide

180675-22-3

C4H7BrMgO2

191.31

0.5 M in Tetrahydrofuran

Heptylmagnesium Bromide

13125-66-1

CH3(CH2)6MgBr

203.40

1.0 M in Diethyl Ether

Octylmagnesium Bromide

17049-49-9

CH3(CH2)7MgBr

217.43

2.0 M in Diethyl Ether

(2-Ethylhexyl)magnesium Bromide

90224-21-8

C8H17BrMg

217.43

1.0 M in in Diethyl Ether

(1,3-Dioxan-2-ylethyl)magnesium Bromide

480438-44-6

C6H11BrMgO2

219.36

0.5 M in Tetrahydrofuran

Nonylmagnesium Bromide

39691-62-8

CH3(CH2)8MgBr

231.46

1.0 M in Diethyl Ether

Decylmagnesium Bromide

17049-50-2

CH3(CH2)9MgBr

245.48

1.0 M in Diethyl Ether

Tetradecylmagnesium Chloride

110220-87-6

CH3(CH2)13MgCl

257.14

1.0 M in Tetrahydrofuran

Dodecylmagnesium Bromide

15890-72-9

CH3(CH2)11MgBr

273.54

1.0 M in Diethyl Ether

Pentane-1,5-di(magnesium Bromide)

23708-48-7

BrMg(CH2)5MgBr

278.55

0.5 M in Tetrahydrofuran

Octadecylmagnesium Chloride

116980-66-6

CH3(CH2)17MgCl

313.24

0.5 M in Tetrahydrofuran

Pentadecylmagnesium Bromide

78887-70-4

CH3(CH2)14MgBr

315.62

0.5 M in Diethyl Ether

 

◆ ALKENE GRIGNARDS ◆

 

 

 

 

 

Vinylmagnesium Chloride

3536-96-7

CH2=CHMgCl

86.80

1.6 M in Tetrahydrofuran

Allylmagnesium Chloride

2622-05-1

CH2=CHCH2MgCl

100.83

2.0 M in Tetrahydrofuran

1-Methyl-2-propenylmagnesium Chloride

21969-32-4

H2C=CHCH(CH3)MgCl

114.86

0.5 M in Tetrahydrofuran

2-Methylallylmagnesium Chloride

5674-01-1

H2C=C(CH3)CH2MgCl

114.86

0.5 M in Tetrahydrofuran

2-Butenylmagnesium Chloride

22649-70-3

CH3CH=CHCH2MgCl

114.86

0.5 M in Tetrahydrofuran

Vinylmagnesium Bromide

1826-67-1

CH2=CHMgBr

131.25

1.0 M in Tetrahydrofuran

1-Propenylmagnesium Bromide

14092-04-7

CH3CH=CHMgBr

145.28

0.5 M in Tetrahydrofuran

Allylmagnesium Bromide

1730-25-2

CH2=CHCH2MgBr

145.28

1.0 M in Diethyl Ether

Isopropenylmagnesium Bromide

13291-18-4

CH2=C(CH3)MgBr

145.28

0.5 M in Tetrahydrofuran

3-Butenylmagnesium Bromide

7103-09-5

H2C=CHCH2CH2MgBr

159.31

0.5 M in Tetrahydrofuran

1-Methyl-1-propenylmagnesium Bromide

85676-85-3

CH3CH=C(CH3)MgBr

159.31

0.5 M in Tetrahydrofuran

2-Methyl-1-propenylmagnesium Bromide

38614-36-7

CH3CH=C(CH3)MgBr

159.31

0.5 M in Tetrahydrofuran

◆ ALKYNE GRIGNARDS ◆

Ethynylmagnesium Bromide

4301-14-8

HC≡CMgBr

129.24

0.5 M in Tetrahydrofuran

Ethynylmagnesium Chloride

65032-27-1

CH≡CMgCl

84.79

0.5 M in Tetrahydrofuran

1-Propynylmagnesium Bromide

16466-97-0

CH3C≡CMgBr

143.26

0.5 M in Tetrahydrofuran

Phenylethynylmagnesium Bromide

6738-06-3

C6H5C≡CMgBr

205.33

1.0 M in Tetrahydrofuran

◆ ARYL GRIGNARDS ◆

2-Methoxyphenylmagnesium Bromide

16750-63-3

CH3OC6H4MgBr

 

1.0 M in Tetrahydrofuran

Phenylmagnesium Chloride

100-59-4

C6H5MgCl

136.86

2.0 M in Tetrahydrofuran

2-Methylphenylmagnesium Chloride

33872-80-9

CH3C6H4MgCl

150.89

1.0 M in Tetrahydrofuran

m-Tolylmagnesium Chloride

121905-60-0

CH3C6H4MgCl

150.89

1.0 M in Tetrahydrofuran

Benzylmagnesium Chloride

6921-34-2

C6H5CH2MgCl

150.89

1.0 M in Diethyl Ether

Benzylmagnesium Chloride

6921-34-2

C6H5CH2MgCl

150.89

2.0 M in Tetrahydrofuran

Phenethylmagnesium Chloride

90878-19-6

C6H5CH2CH2MgCl

164.92

1.0 M in Tetrahydrofuran

4-Methylbenzylmagnesium Chloride

29875-07-8

H3CC6H4CH2MgCl

164.92

 

3-Methylbenzylmagnesium Chloride

29875-06-7

H3CC6H4CH2MgCl

164.92

 

2-Methylbenzylmagnesium Chloride

29875-05-6

H3CC6H4CH2MgCl

164.92

0.25 M in Tetrahydrofuran

3,4-Dimethylphenylmagnesium Chloride

102928-12-1

(CH3)2C6H3MgCl

164.92

0.5 M in Tetrahydrofuran

3-Fluoro-2-methylphenylmagnesium Chloride

480424-74-6

C6H3FCH3MgCl

168.88

 

4-Fluorobenzylmagnesium Chloride

1643-73-8

FC6H4CH2MgCl

168.88

 

4-Methoxybenzylmagnesium Chloride

38769-92-5

CH3OC6H4CH2MgCl

180.91

0.25 M in Tetrahydrofuran

2-Methoxybenzylmagnesium Chloride

480438-46-8

CH3OC6H4CH2MgCl

180.91

0.25 M in Tetrahydrofuran

3-Methoxybenzylmagnesium Chloride

26905-40-8

CH3OC6H4CH2MgCl

180.91

0.25 M in Tetrahydrofuran

Phenylmagnesium Bromide

100-58-3

C6H5MgBr

181.31

3.0 M in Diethyl Ether

Phenylmagnesium Bromide

100-58-3

C6H5MgBr

181.31

1.0 M in Tetrahydrofuran

2-Methyl-2-phenylpropylmagnesium Chloride

35293-35-7

C6H5C(CH3)2CH2MgCl

192.97

0.5 M in Diethyl Ether

4-Methoxyphenethylmagnesium Chloride

211115-05-8

H3COC6H4CH2CH2MgCl

194.94

0.5 M in Tetrahydrofuran

o-Tolylmagnesium Bromide

932-31-0

CH3C6H4MgBr

195.34

2.0 M in Diethyl Ether

p-Tolylmagnesium Bromide

4294-57-9

CH3C6H4MgBr

195.34

1.0 M in Tetrahydrofuran

3-Fluorophenylmagnesium Bromide

17318-03-5

FC6H4MgBr

199.30

1.0 M in Tetrahydrofuran

4-Fluorophenylmagnesium Bromide

352-13-6

FC6H4MgBr

199.30

1.0 M in Tetrahydrofuran

4-Fluorophenylmagnesium Bromide

352-13-6

FC6H4MgBr

199.30

2.0 M in Diethyl Ether

4-Ethylphenylmagnesium Bromide

22873-28-5

C2H5C6H4MgBr

209.37

0.5 M in Tetrahydrofuran

2,3-Dimethylphenylmagnesium Bromide

134640-85-0

(CH3)2C6H3MgBr

209.37

 

2,4-Dimethylphenylmagnesium Bromide

34589-46-3

(CH3)2C6H3MgBr

209.37

0.5 M in Tetrahydrofuran

2,5-Dimethylphenylmagnesium Bromide

30897-86-0

(CH3)2C6H3MgBr

209.37

 

2,6-Dimethylphenylmagnesium Bromide

21450-64-6

(CH3)2C6H3MgBr

209.37

1.0 M in Tetrahydrofuran

3,5-Dimethylphenylmagnesium Bromide

34696-73-6

(CH3)2C6H3MgBr

209.37

0.5 M in Tetrahydrofuran

3,5-Dimethoxybenzylmagnesium Chloride

135808-66-1

C6H3(OCH3)2CH2MgCl

210.94

 

3-Methoxyphenylmagnesium Bromide

36282-40-3

CH3OC6H4MgBr

211.34

1.0 M in Tetrahydrofuran

5-Fluoro-2-methylphenylmagnesium Bromide

186496-59-3

FC6H3(CH3)MgBr

213.33

0.5 M in Tetrahydrofuran

4-Fluoro-3-methylphenylmagnesium Bromide

82297-89-0

FC6H3(CH3)MgBr

213.33

1.0 M in Tetrahydrofuran

3-Fluoro-4-methylphenylmagnesium Bromide

185077-02-5

FC6H3(CH3)MgBr

213.33

0.5 M in Tetrahydrofuran

4-Fluoro-2-methylphenylmagnesium Bromide

30897-90-6

FC6H3(CH3)MgBr

213.33

0.5 M in Tetrahydrofuran

4-Chlorophenylmagnesium Bromide

873-77-8

ClC6H4MgBr

215.76

1.0 M in Diethyl Ether

3-Chlorophenylmagnesium Bromide

36229-42-2

C6H4BrClMg

215.76

 

3,5-Difluorophenylmagnesium Bromide

62351-47-7

F2C6H3MgBr

217.29

0.5 M in Tetrahydrofuran

3,4-Difluorophenylmagnesium Bromide

90897-92-0

F2C6H3MgBr

217.29

0.5 M in Tetrahydrofuran

2,4,6-Trimethylphenylmagnesium Bromide

2633-66-1

(CH3)3C6H2MgBr

223.39

1.0 M in Diethyl Ether

4-n-Propylphenylmagnesium Bromide

87942-08-3

C6H4CH2CH2CH3MgBr

223.39

 

3,5-Dimethyl-4-methoxyphenylmagnesium Bromide

185416-17-5

C6H2CH3CH3OCH3MgBr

223.39

 

2,4,6-Trimethylphenylmagnesium Bromide

2633-66-1

(CH3)3C6H2MgBr

223.39

1.0 M in Tetrahydrofuran

4-(N,N-Dimethyl)aniline magnesium Bromide

7353-91-5

(CH3)2NC6H4MgBr

224.38

0.5 M in Tetrahydrofuran

3,4-(Methylenedioxy)phenylmagnesium Bromide

17680-04-5

C7H5BrMgO2

225.32

1.0 M in toluene/Tetrahydrofuran (50:50)

4-Methoxy-2-methylphenylmagnesium Bromide

148706-30-3

CH3OC6H3(CH3)MgBr

225.37

0.5 M in Tetrahydrofuran

3-Fluoro-6-methoxyphenylmagnesium Bromide

188132-02-7

FC6H3(OCH3)MgBr

229.33

0.5 M in Tetrahydrofuran

3-Fluoro-4-methoxyphenylmagnesium Bromide

112780-67-3

FC6H3(OCH3)MgBr

229.33

 

4-Chloro-2-methylphenylmagnesium Bromide

480438-47-9

ClC6H3(CH3)MgBr

229.78

 

2-Naphthylmagnesium Bromide

21473-01-8

C10H7BrMg

231.37

 

1-Naphthylmagnesium Bromide

703-55-9

C10H7BrMg

231.37

0.25 M in Tetrahydrofuran

3-Chloro-4-fluorophenylmagnesium Bromide

413589-34-1

C6H3BrClFMg

233.75

0.5 M in Tetrahydrofuran

3-Chloro-5-fluorophenylmagnesium Bromide

480438-50-4

ClC6H3(F)MgBr

233.75

0.5 M in Tetrahydrofuran

4-Chloro-3-fluorophenylmagnesium Bromide

170793-00-7

ClC6H3(F)MgBr

233.75

0.5 M in Tetrahydrofuran

3,4,5-Trifluorophenylmagnesium Bromide

156006-28-9

F3C6H2MgBr

235.28

0.3 M in Tetrahydrofuran

4-Butylphenylmagnesium Bromide

185416-14-2

CH3(CH2)3C6H4MgBr

237.42

0.5 M in Tetrhydrofuran

4-tert-Butylphenylmagnesium Bromide

63488-10-8

(CH3)3CC6H4MgBr

237.42

2.0 M in Diethyl Ether

2,4-Dimethoxyphenylmagnesium Bromide

138109-49-6

(CH3O)2C6H3MgBr

241.36

0.5 M in Tetrahydrofuran

2,5-Dimethoxyphenylmagnesium Bromide

62890-98-6

(CH3O)2C6H3MgBr

241.36

0.5 M in Tetrahydrofuran

3,4-Dimethoxyphenylmagnesium Bromide

89980-69-8

(CH3O)2C6H3MgBr

241.36

0.5 M in Tetrahydrofuran

2-Methyl-1-napthylmagnesium Bromide

21450-90-8

C10H6CH3MgBr

245.40

 

4-Methyl-1-naphthylmagnesium Bromide

115913-58-1

C10H6CH3MgBr

245.40

 

3,4-Dichlorophenylmagnesium Bromide

79175-35-2

Cl2C6H3MgBr

250.20

0.5 M in Tetrahydrofuran

3,5-Dichlorophenylmagnesium Bromide

82297-90-3

Cl2C6H3MgBr

250.20

0.5 M in Tetrahydrofuran

4-Biphenylmagnesium Bromide

3315-91-1

C6H5C6H4MgBr

257.41

0.5 M in Tetrahydrofuran

(3-(1-Pyrrolidinylmethyl)phenyl)magnesium Bromide

480424-79-1

C6H4CH2NC4H8MgBr

264.44

 

(4-(1-Pyrrolidinylmethyl)phenyl)magnesium Bromide

480424-78-0

C6H4CH2NC4H8MgBr

264.44

0.25 M in Tetrahydrofuran

(2-(1-Pyrrolidinylmethyl)phenyl)magnesium Bromide

480424-80-4

C6H4CH2NC4H8MgBr

264.44

 

Pentafluorophenylmagnesium Bromide

879-05-0

C6F5MgBr

271.27

0.5 M in Diethyl Ether

4-Phenoxyphenylmagnesium Bromide

21473-02-9

C6H5OC6H4MgBr

273.41

0.5 M in Tetrahydrofuran

3-Bromobenzylmagnesium Bromide

107549-22-4

BrC6H4CH2MgBr

274.24

0.25 M in Diethyl Ether

2-Bromobenzylmagnesium Bromide

56812-60-3

BrC6H4CH2MgBr

274.24

0.25 M in Diethyl Ether

[2-(1-Piperidinylmethyl)phenyl]magnesium Bromide

480424-81-5

C6H4CH2NC5H10MgBr

278.47

0.25 M in Tetrahydrofuran

(4-(1-Piperidinylmethyl)phenyl)magnesium Bromide

480424-83-7

C6H4CH2NC5H10MgBr

278.47

0.25 M in Tetrahydrofuran

[3-(1-Piperidinylmethyl)phenyl]magnesium Bromide

480424-82-6

C6H4CH2NC5H10MgBr

278.47

0.25 M in Tetrahydrofuran

[2-(4-Morpholinylmethyl)phenyl]magnesium Bromide

480424-77-9

C11H14BrMgNO

280.44

 

(3-(4-Morpholinylmethyl)phenyl)magnesium Bromide

480424-76-8

C6H4CH2NOC4H8MgBr

280.44

0.25 M in Tetrahydrofuran

4-(2-Tetrahydro-2H-pyranoxy)phenylmagnesium Bromide

36637-44-2

C11H13BrMgO2

281.43

0.5 M in Tetrahydrofuran

9-Phenanthrylmagnesium Bromide

71112-64-6

C14H9BrMg

281.43

 

3-[Bis(trimethylsilyl)amino]phenylmagnesium Chloride

174484-84-5

[(CH3)3Si]2NC6H4MgCl

296.24

1.0 M in Tetrahydrofuran

 

◆ THIO GRIGNARDS ◆

 

Thiophen-2-yl-magnesium Bromide

5713-61-1

C4H3BrMgS

187.34

1.0 M in Tetrahydrofuran

3-Methyl-2-thienylmagnesium Bromide

95184-07-9

C5H5BrMgS

201.37

0.5 M in Tetrahydrofuran

5-Chloro-2-thienylmagnesium Bromide

111762-30-2

C4H2BrClMgS

221.79

 

4-Thioanisolemagnesium Bromide

18620-04-7

H3CSC6H4MgBr

227.40

0.5 M in Tetrahydrofuran

3-Thienylmagnesium iodide

172035-86-8

C4H3IMgS

234.34

0.5 M in Tetrahydrofuran