7-AZAINDOLE

PRODUCT IDENTIFICATION

CAS NO. 271-63-6

7-AZAINDOLE

EINECS NO. 205-981-0
FORMULA C7H6N2
MOL WT. 118.14

H.S. CODE

2933.99.7900

TOXICITY

 
SYNONYMS 1,7-Diazaindene; 7-Aza-1-pyrindine; Pyrrolo(2,3-b)pyridine;
1H-Pyrrolo[2,3-b]pyridine; 1H-Pirrolo[2,3-b]piridina; 1H-Pyrrolo[2,3-b]pyridine; 1,7-Dideazapurine; 7-Azaindole
SMILES c12c([nH]cc1)nccc2

CLASSIFICATION

 

EXTRA NOTES

Starting material in the synthesis of azaserotonin.

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE White to off-white crystalline powder
MELTING POINT 105 - 107 C
BOILING POINT

 

SPECIFIC GRAVITY

 

SOLUBILITY IN WATER Soluble in hot water
pH  
VAPOR DENSITY

 

AUTOIGNITION  

REFRACTIVE INDEX

 

NFPA RATINGS Health: 1; Flammability: 0; Reactivity: 0
FLASH POINT

 

STABILITY Stable under normal conditions. Light sensitive

EXTERNAL LINKS & GENERAL DESCRIPTION

Wikipedia Linking

Google Scholar Search

Drug Information Portal (U.S. National Library of Medicine) - 7-Azaindole

PubChem Compound Summary - 7-Azaindole

http://www.ebi.ac.uk/chebi/ -  7-Azaindole

http://www.ncbi.nlm.nih.gov/ -  7-Azaindole

Material Safety Data Sheet

http://pubs.rsc.org/
7-Azaindole and its derivatives have been extensively investigated for uses in biological probes and imaging. In contrast, there have been very limited studies on the coordination chemistry and the applications of 7-azaindole and derivatives in materials science and in chemical bond activation. Our recent research has shown that 7-azaindolyl and derivatives are excellent blue emitters for organic light emitting diodes, they have rich coordination chemistry with both main group elements and transition metal ions, and their metal complexes display not only phosphorescence but also unusual and often unprecedented reactivity toward C–H and C–X bonds. This critical review discusses recent advances in these fields with focuses on new 7-azaindolyl derivatives and their metal complexes developed by our group. The luminescent properties and applications of 7-azaindolyl-based compounds will be presented. The reactivity of Pt(II) complexes toward C–H and C–X bonds, especially the steric impact of the bis(7-azaindolyl) chelate ligands and bimetallic cooperativity will be discussed (86 references).

Local:
Indole, also called Benzopyrrole, is a yellow crystalline powder with unpleasant aroma. It has the pyrrole ring (five-membered unsaturated ring structure composed of four carbon atoms and one nitrogen atom) which is fused benzene ring. There are tautomerer called indolenine (unsubstituted 3H-indole) and structural isomer, isoindole. But they are unstable. Indole occurs in some plants or in coal tar, and is formed in the intestine during putrefaction and by certain cultures of bacteria. it is commercially synthesized from phenylhydrazine and pyruvic acid. It is used in perfumery and in preparing tryptophan, one of the 20 amino acids commonly found in animal proteins. It has important application in the industry of plant growth. It is used to to prepare indoleacetic acid (auxin) and other plant growth substances which help the development of roots in plant. It is used to make selective herbicides. Indole and its derivatives are widely used in making perfumes, agrochemicals and medicines.

SALES SPECIFICATION

APPEARANCE

white to slight yellow crystalline powder
ASSAY (G.C)

98.0% min

MOISTURE (K.F.)

0.5% max

LOSS ON DRYING

1.0% max

TRANSPORTATION
PACKING  
HAZARD CLASS 6.1 (Packing group : III)
UN NO. 2811
SAFETY INFORMATION

HAZARD OVERVIEW

OSHA Hazards: Irritant

GHS

 

SIGNAL WORD Warning

PICTOGRAMS

HAZARD STATEMENTS

H302-H315-H318-H335

P STATEMENTS

P261-P280-P305 + P351 + P338

EC DIRECTIVES

 

HAZARD CODES

RISK PHRASES

22-37/38-41

SAFETY PHRASES

26-36/37/39

PRICE INFORMATION