TRIDEMORPH

PRODUCT IDENTIFICATION
CAS NO. 24602-86-6; 81412-43-3

TRIDEMORPH

EINECS NO. 246-347-3
FORMULA C19H39NO
MOL WT. 297.52

H.S. CODE

  

TOXICITY

  
SYNONYMS Kalinin; Calixine; N-Tridecyl-2,6-dimethylmorpholin;
2,6-Dimethyl-4-tridecylmorpholine; 4-Tridecyl-2,6-dimethylmorpholine; n-Tridecyl-2,6-dimethylmorpholine; Dimethyl-2,6 tridecyl-4 morpholine; Tridemorphe;
SMILES

 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE yellow oily liquid
MELTING POINT  
BOILING POINT

134 C

SPECIFIC GRAVITY

 

SOLUBILITY IN WATER Insoluble (soluble in most organic solvents)
pH 7 - 8
VAPOR DENSITY

 

REFRACTIVE INDEX

  
AUTOIGNITION

 

NFPA RATINGS Health: 2; Flammability: 1; Reactivity: 0
FLASH POINT

 

STABILITY

Stable under ordinary conditions

APPLICATIONS
Morpholine fungicides are classified as compounds with a low risk of resistance development in the target organism because they act at several sites. In contrast, barley powdery mildew, being a wind dispersed, highly sporulating, polycyclic pathogen with many asexual generations in a single season, belongs to the group of high risk fungi as far as fungicide resistance is concerned. Morpholines have been the main source of control of barley powdery mildew in the UK since triazole resistance became widespread in the mid -1980s. With a high selection pressure on the mildew population, there is a risk of fungicide resistance developing in this pathogen. As part of a programme to assess this risk, the morpholine sensitivity of mildew isolates was measured to determine whether the use of morpholine fungicides on cereals was associated with any change in the sensitivity to morpholines in the pathogen isolated from these crops. The fungicide sensitivity of isolates was then related to the previous history of the crop which were grouped as those collected from crops with no history of fungicide use, isolates obtained from different geographical regions and isolates obtained over several seasons, 1991-1994. (source: The British Society for Plant Pathology)

Several morpholine derivatives, e.g., morpholinium salts of certain acylated sulfonamides, possess bactericidal activity. Morpholine hydroperiodide has been used as a water disinfectant (Texaco, 1986). Morpholine fungicides are used for agricultural purposes (Mercer, 1991), as foliar fungicides with protective and curative properties for the control of powdery mildew and rust (Brouwers et al., 1992; Leenheers et al. 1992), and as foliar fungicides for cereals (Ackermann et al., 1989). Morpholine is also used in the preparation of herbicides that can be applied either to the soil before the weeds emerge or to the growing plants (Texaco, 1986). (source: IPCS INCHEM)

Morpholine fungicides

Product

CAS RN.

Dodemorph

 1593-77-7

Benzamorf

 12068-08-5

Tridemorph

 24602-86-6; 81412-43-3

Carbamorph

 31848-11-0

Fenpropimorph

 67306-03-0

Aldimorph

 91315-15-0

Dimethomorph

 110488-70-5

Flumorph

 211867-47-9

SALES SPECIFICATION

APPEARANCE

 yellow oily liquid

ASSAY

98.0% min
pH 7 - 8

MOISTURE

0.5% max
TRANSPORTATION
PACKING

 

HAZARD CLASS 9 (Packing group: III)
UN NO. 3082
OTHER INFORMATION
Hazard Symbols: T N, Risk Phrases: 61-20/22-38-50/53, Safety Phrases: 53-45-60-61