3-HEXENOL

PRODUCT IDENTIFICATION

CAS NO. 928-96-1

3-HEXENOL

EINECS NO. 213-192-8
FORMULA C2H5CH=CHCH2CH2OH
MOL WT. 100.16

H.S. CODE

2905.29.9000

TOXICITY

Oral Rat LD50: 600mg/kg
SYNONYMS 3-Hexen-1-ol; 3-Hexenol; Leaf alcohol; (Z)-3-Hexen-1-ol;
(Z)-Hex-3-en-1-ol; cis-3-Hexen-1-ol; Blatteralkohol; Z-3-Hexenol; beta-gamma-Hexenol; Other RN: 95123-47-0
SMILES C(=C/CC)\CCO

CLASSIFICATION

Flavor and Fragrance agent

EXTRA NOTES

A green odor chemical. FEMA No. 2563.

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE
clear to yellowish liquid
MELTING POINT  
BOILING POINT

155 - 157 C

SPECIFIC GRAVITY

0.846 - 0.85

SOLUBILITY IN WATER Insoluble
SOLVENT SOLUBILITY Soluble in alcohol, propylene glycol
VAPOR DENSITY

 

log Pow 1.61
OH RATE CONSTANT 1.10E-10 (cm3/molecule-sec at 25 C Atmospheric)

REFRACTIVE INDEX

1.438 - 1.441

NFPA RATINGS

Health hazard: 1, Flammability: 2, Instability: 0

AUTOIGNITION

 

FLASH POINT

44 C

STABILITY

Stable under ordinary conditions

EXTERNAL LINKS & GENERAL DESCRIPTION

Wikipedia Linking

Google Scholar Search

http://www.landesbioscience.com
Green leaf C6-volatiles are among the most important herbivore-induced plant volatiles (HIPVs). They play important roles in mediating the behavior of herbivores and their natural enemies, and in triggering the plant-plant communication to prevent further attacks. Recently, wound-induced ubiquitous (Z)-3-hexenol, a C6-alcohol synthesized in the lipoxygenase/HPL pathway, was proved to be the most important infochemical for the herbivore repellence/attraction and natural enemy attraction in tritrophic interactions, as well as for the induction of gene expression in neighboring unattacked plants. In spite of the conflict functions of (Z)-3-hexenol in direct and indirect plant defenses, its positive roles in the indirect defense and the priming effect are consistent. Therefore, this compound can be used to develop novel insect pest control strategies.

http://www.chemicalland21.com/
Flavouring Substances Chemical Group 4 (
Non-conjugated and accumulated unsaturated straight-chain and branched-chain aliphatic primary alcohols/aldehydes/acids, acetals and esters with esters containing unsaturated alcohols and acetals containing unsaturated alcohols or aldehydes. No aromatic or heteroaromatic moiety as a component of an ester or acetal.

SALES SPECIFICATION

APPEARANCE

clear to yellowish liquid

ASSAY

98.0% min (sum of enantiomers)

TRANSPORTATION
PACKING
 
HAZARD CLASS 3 (Packing Group: III)
UN NO. 1987
SAFETY INFORMATION
Hazard Symbols: XN, Risk Phrases: 21/22, Safety Phrases: 36/37
PRICE INFORMATION