SULFAMIDE

PRODUCT IDENTIFICATION

CAS NO. 7803-58-9

SULFAMIDE

EINECS NO. 232-262-9
FORMULA H2NSO2NH2
MOL WT. 96.11

H.S. CODE

 

TOXICITY

 

SYNONYMS Sulfonyl Diamine; Sufuric Diamide;
SMILES

 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE white crystalline powder
MELTING POINT 89 - 93 C
BOILING POINT

 

SPECIFIC GRAVITY 1.61
SOLUBILITY IN WATER soluble
pH 6.1
VAPOR DENSITY

 

AUTOIGNITION

 

NFPA RATINGS

 

REFRACTIVE INDEX

 
FLASH POINT

 

STABILITY

Stable under ordinary conditions. Moisturesensitive

APPLICATIONS

Amide is a group of organic chemicals with the general formula RCO-NH2 in which a carbon atom is attached to oxygen in double bond and also attached to an hydroxyl group, where 'R' groups range from hydrogen to various linear and ring structures or a compound with a metal replacing hydrogen in ammonia such as sodium amide, NaNH2. Amides are divided into subclasses according to the number of substituents on nitrogen. The primary amide is formed from by replacement of the carboxylic hydroxyl group by the NH2, amino group. An example is acetamide (acetic acid + amide). Amide is obtained by reaction of an acid chloride, acid anhydride, or ester with an amine. Amides are named with adding '-ic acid' or '-oic acid' from the name of the parent carboxylic acid and replacing it with the suffix 'amide'. Amide can be formed from ammonia (NH3). The secondary and tertiary amides are the compounds which one or both hydrogens in primary amides are replaced by other groups. The names of secondary and tertiary amides are denoted by the replaced groups with the prefix capital N (meaning nitrogen) prior to the names of parent amides. Low molecular weight amides are soluble in water due to the formation of hydrogen bonds. primary amides have higher melting and boiling points than secondary and tertiary amides. Anilide is an amide derived from aniline by substitution of an acyl group for the hydrogen of NH2. Acetanilide is from acetic acid and aniline. Acetanilide is an odourless, white flake solid or crystalline powder (pure form); soluble in hot water alcohol, ether, chloroform, acetone, glycerol, and benzene;; melting point 114 C and boiling point 304 C; can undergo self-ignite at 545 C, but is otherwise stable under most conditions. Acetanilide which can be obtained by acetylation of aniline undergoes nitration at low temperature and yields highly the para-nitro products. Acetyl group can then be removed by acid-catalyzed hydrolysis to yield para-nitroaniline. Although the activating affection of the amino group can be reduced, the acetyl derivative remains an ortho/para-orientation and activating substituent. Examples of aromatic anilide are benzanilide, C6H5NHCOC6H5 or Carbanilide (N,N'-diphenylcarbamide). Some structural amides are;
  • Acetamides
  • Acrylamides
  • Anilides
  • Benzamides
  • Naphthylamides
  • Formamides
  • Lactams
  • Salicylamides
  • Sulfonamides
  • Thioamides
  • Fatty amides

An amide is hydrolyzed to yield an amine and a carboxylic acid under strong acidic conditions. The reverse of this process resulting in the loss of water to link amino acids is wide in nature to form proteins, the principal constituents of the protoplasm of all cells. Sulfonamides are analogs of amides in which the atom attached to oxygen in double bond is sulfur rather than carbon. Polyamide is a polymer containing repeated amide groups such as various kinds of nylon and polyacrylamides.

In pharmaceutical preparation, sulfamide is used as an intermediate for especially anti-ulcer agents.

SALES SPECIFICATION

APPEARANCE

white crystalline powder

ASSAY

99.0% min

MELTING POINT 89 - 93 C

LOSS ON DRYING

0.5% max

Cl

0.1% max

RESIDUE ON IGNITION

0.5% max

TRANSPORTATION
PACKING
40kgs in fiber drum
HAZARD CLASS  
UN NO.  
REMARKS
Hazard Symbols: n/a, Risk Phrases: n/a , Safety Phrases: 24/25/28A/37/45