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SULFAMIDE | ||
PRODUCT IDENTIFICATION |
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CAS NO. | 7803-58-9 |
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EINECS NO. | 232-262-9 | |
FORMULA | H2NSO2NH2 | |
MOL WT. | 96.11 | |
H.S. CODE |
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TOXICITY |
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SYNONYMS | Sulfonyl Diamine; Sufuric Diamide; | |
SMILES |
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CLASSIFICATION |
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PHYSICAL AND CHEMICAL PROPERTIES |
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PHYSICAL STATE | white crystalline powder | |
MELTING POINT | 89 - 93 C | |
BOILING POINT |
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SPECIFIC GRAVITY | 1.61 | |
SOLUBILITY IN WATER | soluble | |
pH | 6.1 | |
VAPOR DENSITY |
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AUTOIGNITION |
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NFPA RATINGS |
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REFRACTIVE INDEX |
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FLASH POINT |
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STABILITY |
Stable under ordinary conditions. Moisturesensitive | |
APPLICATIONS |
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Amide is a group
of organic chemicals with the general formula RCO-NH2 in which a carbon
atom is attached to oxygen in double bond and also attached to an hydroxyl
group, where 'R' groups range from hydrogen to various linear and ring
structures or a compound with a metal replacing hydrogen in ammonia such as
sodium amide, NaNH2. Amides are divided
into subclasses according to the number of substituents on nitrogen. The primary
amide is formed from by replacement of the carboxylic hydroxyl group by the NH2,
amino group. An example is acetamide (acetic acid + amide). Amide is obtained by
reaction of an acid chloride, acid anhydride, or ester with an amine. Amides are
named with adding '-ic acid' or '-oic acid' from the name of the parent
carboxylic acid and replacing it with the suffix 'amide'. Amide can be formed
from ammonia (NH3). The secondary and
tertiary amides are the compounds which one or both hydrogens in primary amides
are replaced by other groups. The names of secondary and tertiary amides are
denoted by the replaced groups with the prefix capital N (meaning nitrogen)
prior to the names of parent amides. Low molecular weight amides are soluble in
water due to the formation of hydrogen bonds. primary amides have higher melting
and boiling points than secondary and tertiary amides. Anilide is an amide derived from aniline by substitution of an acyl group for
the hydrogen of NH2. Acetanilide is from acetic acid and aniline. Acetanilide is an odourless,
white flake solid or crystalline powder (pure form);
soluble in hot water alcohol, ether, chloroform,
acetone, glycerol, and benzene;; melting point 114 C and boiling point 304 C;
can undergo self-ignite at 545 C, but is
otherwise stable under most conditions. Acetanilide which can be obtained by
acetylation of aniline
undergoes
nitration at low temperature and yields highly the para-nitro products. Acetyl group can then be removed by acid-catalyzed hydrolysis to yield para-nitroaniline. Although the activating affection
of the
amino group can be reduced, the acetyl derivative remains an
ortho/para-orientation and activating substituent. Examples of
aromatic anilide are
benzanilide,
C6H5NHCOC6H5 or
Carbanilide (N,N'-diphenylcarbamide). Some structural amides are;
An amide is hydrolyzed to yield an amine and a carboxylic acid under strong acidic conditions. The reverse of this process resulting in the loss of water to link amino acids is wide in nature to form proteins, the principal constituents of the protoplasm of all cells. Sulfonamides are analogs of amides in which the atom attached to oxygen in double bond is sulfur rather than carbon. Polyamide is a polymer containing repeated amide groups such as various kinds of nylon and polyacrylamides. In pharmaceutical preparation, sulfamide is used as an intermediate for especially anti-ulcer agents. |
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SALES SPECIFICATION | ||
APPEARANCE |
white crystalline powder | |
ASSAY |
99.0% min |
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MELTING POINT | 89 - 93 C | |
LOSS ON DRYING |
0.5% max |
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Cl |
0.1% max |
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RESIDUE ON IGNITION |
0.5% max |
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TRANSPORTATION | ||
PACKING | 40kgs
in fiber drum | |
HAZARD CLASS | ||
UN NO. | ||
REMARKS | ||
Hazard Symbols: n/a, Risk Phrases: n/a , Safety Phrases: 24/25/28A/37/45 |
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