1,8-DINITRONAPHTHALENE

PRODUCT IDENTIFICATION

CAS NO. 602-38-0

1,8-DINITRONAPHTHALENE

EINECS NO. 210-016-1
FORMULA C10H6(NO2)2
MOL WT. 218.17
H.S. CODE 2904.20
TOXICITY  
SYNONYMS Naphthalene, 1,8-Dinitro- ;
SMILES
 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE Yellow Crystalline Powder
MELTING POINT 171 - 172 C (97 %)
BOILING POINT  
SPECIFIC GRAVITY

 

SOLUBILITY IN WATER 0.1 g/100ml
AUTOIGNITION  
pH  
VAPOR DENSITY 7.51
NFPA RATINGS Health: ; Flammability: ; Reactivity:
FLASH POINT

 

STABILITY This compound is sensitive to heat and shock

APPLICATIONS

The prefix nitro- indicates the presence of NO2- radical, while nitrate refers to any salt or ester of nitric acid or the NO3- anion. Nitroso- is the prefix indicating presence of the group -NO and azo- is for -N=N- group. Some range of  organic compounds containing nitrogen include nitro compounds (RNO2 ), nitroso compounds (RNO), amines (R3N ), amino acids, and natural alkaloids or nucleotides. The nitrogen ion in nitro compounds is trigonally planar with 120° angles. There are two resonance bonds so that the two oxygens are equivalent. Nitro compounds are strongly basic due to electron withdrawing both inductively and mesomerically. Historically, they are abundant in dyes and explosives. Nitro compounds, organic hydrocarbons having one or more NO2 groups bonded via nitrogen to the carbon framework, are versatile intermediate in organic synthesis.
  • Michael addition
  • Reduction
  • Henry Reaction (Nitro-aldol reaction)
  • Nef reaction
  • O-Alkylation
  • Cycloaddition
  • Substitution, Elimination, Conversion reaction
  • Alkylation, Acylation, and Halogenation

1,8-Dinitronaphthalene is an intermediate for colorants (especially for sulfur colors) and other organic synthesis.

SALES SPECIFICATION

APPEARANCE

Yellow Crystalline Powder
PURITY (G.C)

90.0% min

1,5 ISOMER

6.0% max

OTHER ISOMER

4.0% max

MELTING POINT

158 - 160 C

TRANSPORTATION
PACKING 25kgs in Bag
HAZARD CLASS  
UN NO.  
GENERAL DESCRIPTION OF NAPHTHALENE
Naphthalene is a white, volatile aromatic hydrocarbon with characteristic odor; insoluble in water, somewhat soluble in methanol/ethanol, soluble in organic solvents and very soluble in ether, chloroform, or carbon disulfide. Commercially it is available in molten form or in flaked form. It has the molecular structure of two fused or condensed benzene rings sharing two adjacent carbon atoms; C10H8. Naphthalene is obtained from coal tar which is distilled in the temperature range of 170 - 230 C and is treated with a sodium hydroxide solution to remove phenols. Naphthalene is obtained by the isolation from pyrolysis residue oils, olefin fractions, and petroleum-derived fractions. The distribution capacity is supposed to be about 60% coal-tar and 40% petroleum-derived naphthalene in U.S.A. It is an important parent material to produce numerous substitution products used in the manufacture of dyes, insecticides, organic solvents and synthetic resins. Phthalic anhydride is prepared by oxidizing naphthalene to be used in the manufacture of dyes, resins, plasticizers, and insecticides. Naphthalene sulfonate surfactants and dispersants, however, have increased their market share significantly and are expected to drive whatever growth there is for naphthalene. Naphthalene is the major raw material for Carbaryl, used as a general-purpose insecticide. Naphthalene is also used for moth repellents, fungicides, lubricants, explosives, wood preservatives, vermicides and hydronaphthalenes (tetralin, decalin). Hydronaphthalenes are used for major raw material for dyes, resins, plasticizers, and insecticides. They are also used in reactive and process solvents, heat transfer fluid, dye carrier,  fuel additives, lubricants, ore flotation and oilfield chemicals.