| CAS
NO. |
936-49-2 |
|
| EINECS
NO. |
213-313-4 |
| FORMULA |
C9H10N2 |
| MOL
WT. |
146.19 |
| H.S.
CODE |
|
| TOXICITY |
|
| SYNONYMS |
4,5-dihydro-2-phenyl-1H-Imidazole;
2-Phenyl-2-imidazolin (German); |
|
2-Phényl-2-imidazoline (French); 2-Fenil-2-imidazolina
(Spanish); |
|
SMILES |
|
|
CLASSIFICATION
|
|
|
PHYSICAL AND CHEMICAL PROPERTIES
|
| PHYSICAL
STATE |
white
powder
|
| MELTING POINT |
96 -
101C |
| BOILING
POINT |
|
| SPECIFIC GRAVITY |
|
| SOLUBILITY
IN WATER |
|
| pH |
|
| VAPOR DENSITY |
|
|
AUTOIGNITION
|
|
|
NFPA
RATINGS
|
Health: 1 Flammability: 1 Reactivity: 0 |
|
REFRACTIVE
INDEX
|
|
|
FLASH
POINT
|
201
C
|
| STABILITY |
Stable
under ordinary conditions. |
|
GENERAL
DESCRIPTION AND APPLICATIONS
|
Imidazolidine is the hydrogen-saturated analogue of imidazole
and imidazoline dihydrogenated one. Imidazoline has
a single solid bond but imidazolidine has no solid
bond. The resonance structures of
imidazole keep the aromaticity intact. Imidazole is a base and an excellent nucleophile. It reacts at the NH nitrogen.
Generaly nucleophilic substitutions at the carbon atoms
except C-2 are
difficult with imidazole. But It is susceptible to electrophilic attacks at the carbon atoms
with imidazoline and imidazolidine. Imidazoline
molecules are sympathomimetic agents effecting on alpha-adrenergic
receptors primarily
and little effecting on
beta-adrenergic receptors. The imidazoline derivatives
of adrenergic alpha-agonist include
oxymetazoline
(CAS
RN: 1491-59-4)
, xylometazoline (CAS
RN: 526-36-3), tetrahydrozoline
(CAS
RN: 84-22-0) , and naphazoline (CAS
RN: 835-31-4), They are found in topical ophthalmic and nasal decongestants. Imidazoline
and imidazolidine derivatives acts as a chain
extender in polymerization process and can form thermally stable
polymeric products. Protonated adducts can be used as a curing agent and in
aqueous
electrocoating baths.Adducts of imidazolidine compounds are utilized as a heterocyclic
ligand in
transition-metal coordination chemistry. Alkyl imidazolines are used as a microbiocide,
algaecide or fungicide used in fuel and oil. Members
are as follow:
|
Product
|
CAS
RN
|
| Stearyl imidazoline |
95-19-2 |
| Glyoxide |
105-28-2 |
| Glyodin |
556-22-9 |
| Imidazoline acetate |
12379-40-7 |
| 2-Heptadecyl-1-methyl-1-(octadecanamidoethyl)imidazolinium methosulfate |
13470-50-3 |
| 1-(2-Hydroxyethyl)-2-heptadecenyl-2-imidazoline |
27136-73-8 |
| 2-Heptadecenyl-2-imidazoline |
30968-43-5 |
| Heptadecyl hydroxyethyl imidazoline |
53466-91-4 |
| 2-Heptadecyl-1-hydroxyethyl-imidazolinium hydrochloride |
53466-92-5 |
| Tall oil hydroxyethyl imidazoline |
61791-39-7 |
| 2-(Coco alkyl)-1-benzyl-1-(2-hydroxyethyl)-2-imidazolinium chloride |
61791-52-4 |
| 1,3-Bis(2-hydroxyethyl)-2-heptadecenyl imidazolinium chloride |
76069-38-0 |
| Heptadecenyl imidazolinium chloride |
82078-98-6 |
2-Phenyl-2-imidazoline
is used in formulating epoxy curing agents.
|
| SALES
SPECIFICATION |
|
APPEARANCE
|
white powder
|
| ASSAY |
99.0%
min
|
| MELTING POINT |
96 - 101 C |
| TRANSPORTATION |
| PACKING |
25kgs
in fiber drum |
| HAZARD CLASS |
|
| UN
NO. |
|
| OTHER
INFORMATION |
|
Hazard
Symbols: XI, Risk Phrases: 22-36/37/38,
Safety Phrases: 26-36 |