4-FLUOROBENZALDEHYDE

PRODUCT IDENTIFICATION
CAS NO.

459-57-4

4-FLUOROBENZALDEHYDE

EINECS NO. 207-293-6
FORMULA FC6H4CHO
MOL WT. 124.11
H.S. CODE  
TOXICITY  
SYNONYMS p-Fluorobenzaldehyde;
SMILES 
 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE colorless to yellow liquid
MELTING POINT -10 C
BOILING POINT 180 C
SPECIFIC GRAVITY 1.16
SOLUBILITY IN WATER immiscible
AUTOIGNITION  
pH  
VAPOR DENSITY 4.3
NFPA RATINGS  

REFRACTIVE INDEX

 1.5200
FLASH POINT

56 C

STABILITY Stable under ordinary conditions. Oxidizes in light

GENERAL DESCRIPTION & APPLICATIONS
Benzaldehyde(also called Benzenecarbonal) is the simplest representative of the aromatic aldehydes. It is a colorless liquid aldehyde with a characteristic almond odor. It boils at 180°C, is soluble in ethanol, but is insoluble in water. Benzaldehyde is formed by partial oxidation of benzyl alcohol and readily oxidized to benzoic acid and is converted to addition products by hydrocyanic acid or sodium bisulfite. It is also prepared by oxidation of toluene or benzyl chloride or by treating benzal chloride with an alkali, e.g., sodium hydroxide. It is used chiefly in the synthesis of other organic compounds, ranging from pharmaceuticals to plastic additives and benzaldehyde is an important intermediate for the processing of perfume and flavouring compounds and in the preparation of certain aniline dyes . It is the first step in the synthesis for fragrances. It undergoes simultaneous oxidation and reduction with alcoholic potassium hydroxide, giving potassium benzoate and benzyl alcohol. It is converted to benzoin with alcoholic potassium cyanide, with anhydrous sodium acetate and acetic anhydride, giving cinnamic acid. Compounds which do not have alpha-hydrogen atoms cannot form an enolate ion and do not undergo electrophilic alpha-substitution and aldol condensation. Aromatic aldehydes such as benzaldehyde and formaldehyde may undergo disproportionation in concentrated alkali (Cannizaro's reaction); one molecule of the aldehyde is reduced to the corresponding alcohol and another molecule is simultaneously oxidized to the salt of a carboxylic acid. The speed of the reaction depends on the substituents in the aromatic ring. Two different types of aldehydes (aromatic and aliphatic) can undergo crossing reaction to form fomaldehyde and aromatic alcohols. 4-Fluorobenzaldehyde is used as an intermediate for the production of pharmaceutical and agrochemicals.
SALES SPECIFICATION

APPEARANCE

 colorless to yellow liquid
ASSAY (G.C)

98.0% min

TRANSPORTATION
PACKING 200kgs in drum
HAZARD CLASS 3 (Packing group: III)
UN NO.

1989

HALO-SUBSTITUTED OR CONTAINING BENZALDEHYDES