CAS
NO |
14221-01-3,
12582-12-6, 136296-64-5 |
|
EINECS NO. |
238-086-9 |
FORMULA |
Pd[(C6H5)3P]4 |
MOL
WT. |
1155.56 |
H.S.
CODE
|
2843.90.0000 |
TOXICITY |
|
SYNONYMS |
Tetra(triphenylphosphine)palladium;
|
MILES
|
c1(ccccc1)P(c1ccccc1)c1ccccc1.c1(ccccc1)P(c1ccccc1)c1ccccc1.
c1(P(c2ccccc2)
c2ccccc2)ccccc1.c1(P(c2ccccc2)c2ccccc2)ccccc1.[Pd] |
CLASSIFICATION
|
Catalyst |
EXTRA
NOTE
|
Light
sensitive
|
PHYSICAL AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
bright yellow powder |
MELTING POINT |
103 - 107
C |
BOILING
POINT |
|
SPECIFIC GRAVITY |
|
SOLUBILITY
IN WATER |
Insoluble |
pH |
|
VAPOR DENSITY |
|
NFPA
RATINGS
|
|
AUTOIGNITION
|
|
REFREACTIVE
INDEX
|
|
FLASH
POINT |
|
STABILITY |
Stable
under ordinary conditions. |
APPLICATIONS
|
Catalyst for
- Negishi coupling
- Suzuki coupling
- Stille
coupling
- Sonogashira coupling reaction
- Allylation, Heck, Hiyama reactions
- Buchwald-Hartwig amination
reaction
- Carbonylation of vinyl iodides,
aldehyde, carboxylic acid, ester
- Reduction reaction of aryl
bromides
- Carbon-tin bond formation
|
SALES
SPECIFICATION |
APPEARANCE
|
bright yellow powder |
ASSAY |
98.0%
min
|
MELTING
POINT |
103 - 107
C |
TRANSPORTATION |
PACKING |
|
HAZARD CLASS |
Not
dangerous goods
|
UN
NO. |
|
OTHER
INFORMATION |
Hazard
Symbols: , Risk Phrases: , Safety Phrases: 22-24/25 |