N-ACETOACETYL-5-CHLORO-o-ANISIDINE

PRODUCT IDENTIFICATION

CAS NO.

52793-11-0

N-ACETOACETYL-5-CHLORO-o-ANISIDINE

EINECS NO. 258-189-2
FORMULA

C11H12ClNO3

MOL WT.

241.68

H.S. CODE

 

TOXICITY

Oral rat LD50: 2000 mg/kg

SYNONYMS AAMOC;
Acetessig-5-chlor-2-methoxyanilid (German); Acetoacet- 5-chloro-2- methoxyanilide;  Acetoacet-5-chloro-2- methoxyanilide;
Acétoacét-5-chloro-2-méthoxy-anilide (French); Acetoaceto-5-cloro-2- metossi- anilide (Italian); N-(5-chloro-2-methoxyphenyl)-3-oxo-Butanamide;
SMILES

 

CLASSIFICATION

DIKETENES /

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE

white to pink powde

MELTING POINT  
BOILING POINT  
SPECIFIC GRAVITY

 

SOLUBILITY IN WATER

Slightly soluble (Ethanol: 50 g/kg , Acetic acid: 320 g/kg )

pH  
VAPOR DENSITY  
FLASH POINT  

APPLICATIONS

Acetoacetic acid and its esters contain active methylene groups which have relatively acidic alpha-protons due to H atoms adjacent to two carbonyl groups. The reactivity of its methylene group provide the sequence of reactions of alkylation, hydrolysis of the esters and decarboxylation resulting in substituted ketones. AAMOC is used as an intermediate for the synthesis of organic Colorants (e.g. PigmentsYellow 172). Acetoacetic acid derivatives are important aliphatic parts adjoining azo dyes and pigments. Anisic acid, p-methoxybenzoic acid, is a part of cresol class antiseptic compounds. It is also used as an insect repellent and ovicide. Anisole, anisic acid, and their deivatives are also widely used in chemical reaction as intermediates to obtain target materials such as dyes, pharmaceuticals, perfumes, photoinitiators and agrochemcials.
SALES SPECIFICATION

APPEARANCE

white to pink powder

ASSAY (TITR.)

99.0 - 100.5%

MELTING POINT

91 - 93 C

TRANSPORTATION
PACKING 25kgs in Bag
HAZARD CLASS TSCA Listed
UN NO. Not Regulated
REMARKS
Arylides are intermediates for organic dyestuffs and pigments.