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(2-BROMOETHOXY)-tert-BUTYLDIMETHYLSILANE |
| Synonyms. (2-Bromoethoxy)-tert-butyldimethylsilane; 2-Bromoethoxy(tert-butyl)dimethylsilane; 2-(tert-Butyldimethylsiloxy)ethylbromide; (tert-Butyldimethylsiloxy)-2-ethylbromide; |
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| PRODUCT IDENTIFICATION | |
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CAS RN |
86864-60-0 |
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EINECS RN |
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FORMULA |
BrCH2CH2OSi(CH3)2C(CH3)3 |
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MOLE WEIGHT |
239.23 |
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H.S CODE |
2931.90.9010 |
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SMILES |
CC(C)(C)[Si](C)(C)OCCBr |
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CLASSIFICATION |
Organosilane |
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EXTRA NOTES |
Application:Reagent for N-protection with the TBSO-ethyl group. Treatment with Jones reagent effects hydrolysis and concomitant oxidation leading to N-acetic acids for further synthetic elaboration. (sigmaaldrich) |
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| PHYSICAL AND CHEMICAL PROPERTIES | |
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PHYSICAL STATE. |
clear to pale yellow liquid |
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MELTING POINT |
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BOILING POINT |
73 C at 2.5 mmHg |
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DENSITY |
1.115 |
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SOLUBILITY IN WATER |
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| SOLVENT SOLUBILITY |
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VAPOR DENSITY |
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log P(octanol-water) |
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VAPOR PRESSURE |
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AUTOIGNITION TEMP |
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| pK |
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REFRACTIVE INDEX |
1.444 |
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FLASH POINT |
73 C |
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| STABILITY AND REACTIVITY | |
| STABILITY | Stable under normal conditions. |
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INCOMPATIBLE MATERIALS |
Strong oxidizing agents |
| POLYMERIZATION |
Has not been reported |
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NFPA RATINGS |
Health: 1, Flammability: 1, Reactivity: 0 |
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| EXTERNAL LINKS & GENERAL DESCRIPTION |
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USA.gov - (2-Bromoethoxy)-tert-butyldimethylsilane Google Scholar Search - (2-Bromoethoxy)-tert-butyldimethylsilane PubChem Compound Summary - (2-Bromoethoxy)-tert-butyldimethylsilane http://www.ncbi.nlm.nih.gov/ - (2-Bromoethoxy)-tert-butyldimethylsilane |
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| SALES SPECIFICATION | |
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APPEARANCE |
clear to pale yellow liquid |
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ASSAY |
99.5% min |
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| TRANSPORT & REGULATORY INFORMATION | |
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UN NO. |
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| HAZARD CLASS |
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| PACKING GROUP | |
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| SAFETY INFORMATION | |
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HAZARD OVERVIEW |
OSHA Hazards: Irritant. GHS (Globally Harmonised System) Classification: Acute toxicity, Oral. Skin irritation. Eye irritation. Specific target organ toxicity - single exposure. Potential Health Effects: Eyes: May cause eye irritation. Skin: May be harmful if absorbed through skin. May cause skin irritation. Inhalation: May be harmful if inhaled. May cause respiratory tract irritation. Ingestion: May be harmful if swallowed. |
| SIGNAL WORD | Warning |
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PICTOGRAMS |
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HAZARD STATEMENTS |
H315-H319-H335 |
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P STATEMENTS |
P261-P305 + P351 + P338 |
| EC DIRECTIVES |
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| HAZARD CODES |
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RISK PHRASES |
36/37/38 |
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SAFETY PHRASES |
26-36 |
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| PACKING |
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Preserve in light-resistant and well-closed containers |
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