BROMOMALONALDEHYDE

Synonyms. Bromomalonaldehyde; Bromomalondialdehyde; 2-Bromopropanedial;

BROMOMALONALDEHYDE

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PRODUCT IDENTIFICATION

CAS RN

2065-75-0

EINECS RN

 

FORMULA

BrCH(CHO)2

MOLE WEIGHT

150.96

H.S CODE

2913.00.5000

SMILES

C(C(C=O)Br)=O

CLASSIFICATION

Aldehyde

EXTRA NOTES

Application: Used in the formation of glyoxal-derived adducts from substituted guanines. Used to construct a 1,4-dihydroquinoline bearing a C-3 chiral sulfoxide group which functions as an annelated NADH model in the enantioselective reduction of methyl benzoylformate to methyl mandelate. (sigmaaldrich)

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE.

white to pale yellow crystalline powder

MELTING POINT

132 ~ 136 C

BOILING POINT

 

DENSITY

 

SOLUBILITY IN WATER

 

SOLVENT SOLUBILITY

 

VAPOR DENSITY

 

log P(octanol-water)

 

VAPOR PRESSURE

 

AUTOIGNITION TEMP

 
pK

 

REFRACTIVE INDEX

 

FLASH POINT

 

 

STABILITY AND REACTIVITY
STABILITY Stable under normal conditions.

INCOMPATIBLE MATERIALS

Strong oxidizing agents

POLYMERIZATION

Has not been reported

NFPA RATINGS

Health: 1, Flammability: 0, Reactivity: 0

 

EXTERNAL LINKS & GENERAL DESCRIPTION

USA.gov - Bromomalonaldehyde

Wikipedia Linking - Malonaldehyde

Google Scholar Search - Bromomalonaldehyde

PubChem Compound Summary - Bromomalonaldehyde

http://www.ncbi.nlm.nih.gov/ -  Bromomalonaldehyde

 

SALES SPECIFICATION

APPEARANCE

white to pale yellow crystalline powder

ASSAY

99% min

MELTING POINT

132 ~ 136 C

LOSS ON DRYING

1.0% max

 

TRANSPORT & REGULATORY INFORMATION

UN NO.

 

HAZARD CLASS

 

PACKING GROUP  

 

SAFETY INFORMATION

HAZARD OVERVIEW

OSHA Hazards: Irritant. GHS (Globally Harmonised System) Classification: Acute toxicity, Oral. Skin irritation. Eye irritation. Specific target organ toxicity - single exposure. Potential Health Effects: Eyes: May cause eye irritation. Skin: May be harmful if absorbed through skin. May cause skin irritation. Inhalation: May be harmful if inhaled. May cause respiratory tract irritation. Ingestion: May be harmful if swallowed.

SIGNAL WORD Warning

PICTOGRAMS

HAZARD STATEMENTS

H315-H319-H335

P STATEMENTS

P261-P305 + P351 + P338

EC DIRECTIVES

 

HAZARD CODES

RISK PHRASES

36/37/38

SAFETY PHRASES

26-36

 

PACKING

Preserve in light-resistant and well-closed containers