DESS-MARTIN PERIODINANE

PRODUCT IDENTIFICATION

CAS NO. 87413-09-0

DESS-MARTIN PERIODINANE

EINECS NO.  
FORMULA C13H13IO8
MOL WT. 424.14

H.S. CODE

2916.39.4500

TOXICITY

 

SYNONYMS (1,1,1-Triacetoxy)-1,1-dihydro-1,2-benziodoxol-3(1H)-one;
Triacetoxyperiodinane;

SMILES

O(C(C)=O)I1(OC(c2c1cccc2)=O)(OC(=O)C)OC(=O)C

CLASSIFICATION

Hypervalent Iodine.

EXTRA NOTES

Oxidizing agent for primary and secondary alcohols to aldehydes and ketones. Used for the oxidation of hydroxychlorins to chlorin-alpha-diones and tetraones.

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE white to off-white crystalline powder
MELTING POINT

131 - 134 C

BOILING POINT  
SPECIFIC GRAVITY 1.362
SOLUBILITY IN WATER  
SOLUBILITY IN SOLVENT Sparingly soluble in hexane, ether. Soluble in chloroform, methylene chloride, acetonitrile and acetone.
pH  
VAPOR DENSITY

 

AUTOIGNITION

 

NFPA RATINGS

 

REFRACTIVE INDEX

 

FLASH POINT

 

STABILITY

Stable under ordinary conditions.

GENERAL DESCRIPTION AND EXTERNAL LINKS

Wikipedia Linking: http://en.wikipedia.org/wiki/Dess-Martin_periodinane

Material Safety Data Sheet: http://www.chemcas.com

Dess-Martin Oxidation: The Dess-Martin Periodinane (DMP), a hypervalent iodine compound, offers selective and very mild oxidation of alcohols to aldehydes or ketones. The oxidation is performed in dichloromethane or chloroform at room temperature, and is usually complete within 0.5 - 2 hours. Products are easily separated from the iodo-compound byproduct after basic work-up. http://www.organic-chemistry.org/
SALES SPECIFICATION

APPEARANCE

white to off-white crystalline powder

ASSAY

97.0% min
MELTING POINT

131 - 134 C

TRANSPORTATION
PACKING
 
HAZARD CLASS  
UN NO.  
OTHER INFORMATION
Hazard Symbols: O, XN, Risk Phrases: 8-40, Safety Phrases: 17-23-24/25-36/37