5-METHYL-2,3-HEXANEDIONE

PRODUCT IDENTIFICATION

CAS NO.

13706-86-0

5-METHYL-2,3-HEXANEDIONE

EINECS NO.  
FORMULA CH3COCOC3H6CH3
MOL WT.

128.17

H.S. CODE

2914.19

TOXICITY

 
SYNONYMS 5-methyl Propyl Diketone; Acetyl isovaleryl; Acetylisopentanoyl;
PRICE

 

CLASSIFICATION

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE yellowish viscous liquid

MELTING POINT

-30 C
BOILING POINT 135 C
SPECIFIC GRAVITY

0.905 - 0.915

SOLUBILITY IN WATER

Insoluble (Soluble in ethanol)
pH 3 - 4
VAPOR DENSITY

 

AUTOIGNITION  

REFRACTIVE INDEX

1.406 - 1.415

NFPA RATINGS  
FLASH POINT 26 C
STABILITY Stable under ordinary conditions

GENERAL DESCRIPTION & APPLICATIONS

Diketone is a molecule which contains two ketone carbonyl groups. Diacetyl (CH3COCOCH3), 2,3-butadione, is the simplest aliphatic diketone. It is an alpha-diketone which has two ketone groups side-by-side. Usually, alpha-diketone imparts a carmel like or buttery flavor. Diketone compounds take a role in creating various fragrances. Bezil (C6H5COCOC6H5) is an aromatic diketone, the fundamental structure of photo sensitive molecule which is broken down into free radicals upon exposure to ultraviolet radiation. Acetoacetone is a beta-diketone which two ketones are separated only by one carbon. The beta-ketone is stable as a conjugated enol rather than a diketone due to the delocalization which makes the counterion more stable and less likely to regain the proton. Ascorbic acid is an example of enol compound. Enol compounds form complexes with many transition metal ions. These compounds are readily soluble in organic solvents. They are widely used as chelating agents, ligands, and catalyst precursors. Acetoacetic acid and its esters contain active methylene groups which have relatively acidic alpha-protons due to H atom adjacent to two carbonyl groups. The reactivity of its methylene group provide the sequence of reactions of alkylation, hydrolysis of the esters and decarboxylation resulting in substituted ketones. Acetoacetic acid derivatives are important aliphatic parts adjoining azo dyes and pigments. Aacetoacetate is one of Ketone bodies which are the end-products of rapid or excessive fatty acid breakdown in the human body. Para-benzoquinone and its derivatives belong to 1,4-diketone family. Benzoquinone is used as an oxidizing agent in organic chemistry and is a common constituent of biologically molecules like Vitamin K1. Quinones serves as electron acceptors in electron transport chains such as in photosynthesis, and aerobic respiration. Diketene derivatives find versatile applications in making biomolecules, agrochemicals, dyes, pigments, pharmaceuticals including vitamins, and stabilizers for PVC and polyester. They are used as components for fragrances and as solvents. Diketones undergo the reversible and irreversible addition reactions include;
  • Aldol Reactions
  • Alkylation of Enolate Anions
  • Clemmensen Reduction
  • Cyanohydrin Formation
  • Enamine Formation
  • Hemiacetal and Acetal Formation
  • Hydration Formation
  • Imine Formation
  • Wolff-Kishner Reduction

5-Methyl-2,3-Hexanedione is used as an ingredient of aroma. Odor description : buttery, cheesy, sweet, nutty, fruity.

SALES SPECIFICATION

APPEARANCE

White to pale yellow crystalline powder
ASSAY (G.C) 95.0% min
SPECIFIC GRAVITY

0.905 - 0.915

TRANSPORTATION
PACKING  
HAZARD CLASS  
UN NO. 1993
OTHER INFORMATION
Hazard Symbols: , Risk Phrases: 10-36/37/38, Safety Phrases: 26-36/37/39
FEMA NO. 3190