CAS
NO. |
625-36-5
|
|
EINECS
NO. |
210-890-4 |
FORMULA |
ClCH2CH2COCl |
MOL
WT. |
126.97 |
H.S.
CODE |
|
TOXICITY |
Very
Toxic Liquid, Corrosiv E |
SYNONYMS |
3-Chloropropionic Acid Chloride; |
Beta-Chloropropanoyl chloride; 3-chloro-Propanoyl chloride;
cloruro de 3-Cloropropionilo (Spanish); Chlorure de 3-chloropropionyle
(French); |
SMILES |
|
CLASSIFICATION
|
|
PHYSICAL AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
clear
to brown liquid
|
MELTING POINT |
-32
C |
BOILING
POINT |
143
- 145 C |
SPECIFIC GRAVITY |
1.33
|
SOLUBILITY
IN WATER |
Combines vigorously
with water |
AUTOIGNITION |
490
C
|
pH |
|
VAPOR DENSITY |
4.4 |
NFPA RATINGS |
Health: 2; Flammability: 3; Reactivity: 2 |
REFRACTIVE
INDEX
|
|
FLASH
POINT |
30
C
|
STABILITY |
reacts violently with water.
|
APPLICATIONS
|
Acid chlorides are used as very reactive intermediates to prepare carboxylic
acid derivatives including anhydrides, esters and amides because of the two
strong electron withdrawing chlorine and oxygen on the carbonyl compound, and
positive charge carbon accordingly. It is easy for a weak nucleophile to attack
the carbon. Acid chlorides are also reactive with Gilman reagents to prepare
large molecules from small ones by replacing the halides with an organic group.
3-Chloropropionyl
chloride,
an acid chlorides with an additional chloride at
the terminal carbon, is a clear to yellowish liquid
with a pungent odor; melting point -32 C. It hydrolyses
with water. It
must be protected against moisture, air, light and
heat during storage and handling. It is used in
the preparation of pharmaceuticals (an example is Beelamide Proxazole),
agrochemicals, peroxides and other target molecules
such as dyes (disperse violet)
and textile auxiliaries. |
SALES
SPECIFICATION |
APPEARANCE
|
clear
to brown
liquid
|
ASSAY
(G.C) |
98.0%
min
|
ACRYLIC
ACID CHLORIDE
|
0.5%
max
|
TRANSPORTATION |
PACKING |
220ks
in Drum |
HAZARD CLASS |
6.1
(Packing group: II) |
UN
NO. |
2927 |
OTHER
INFORMATION |
Hazard
Symbols: T+ C, Risk Phrases: 14-22-26-34, Safety Phrases: 23-26-36/37/39-45 |
PRICES
|
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